Baghdad Battery

Drawing of the three pieces.

The term Baghdad Battery is used to refer to three artifacts which were found together: a ceramic pot, a tube of one metal, and a rod of another. The current interpretation of their purpose is as a storage vessel for sacred scrolls from nearby Seleucia on the Tigris. Those vessels do not have the outermost clay jar, but are otherwise almost identical.

Wilhelm König was a professional painter who was an assistant at the National Museum of Iraq in the 1930s. In 1938 he authored a paper offering the hypothesis that they may have formed a galvanic cell, perhaps used for electroplating gold onto silver objects. This interpretation is generally rejected today.

In March 2012, Professor Elizabeth Stone, of Stony Brook University, an expert on Iraqi archaeology, returning from the first archaeological expedition in Iraq after 20 years, stated that she does not know a single archaeologist who believed that these were batteries.

Physical description

The artifacts consist of terracotta pots approximately 130 mm (5 in) tall (with a one-and-a-half-inch mouth) containing a cylinder made of a rolled copper sheet, which houses a single iron rod. At the top, the iron rod is isolated from the copper by bitumen, which plugs or stoppers, and both rod and cylinder fit snugly inside the opening of the jar. The copper cylinder is not watertight, so if the jar were filled with a liquid, this would surround the iron rod as well. The artifact had been exposed to the weather and had suffered corrosion.

König thought the objects might date to the Parthian period (between 250 BC and AD 224); but according to St John Simpson of the Near Eastern department of the British Museum, their original excavation and context were not well-recorded (see stratigraphy), so evidence for this date range is very weak. Furthermore, the style of the pottery (see typology) is Sassanid (224-640).

Most of the components of the objects are not particularly amenable to advanced dating methods. The ceramic pots could be analysed by thermoluminescence dating, but this has not yet been done; in any case, it would only date the firing of the pots, which is not necessarily that of the complete artifact.

Speculation

Some believe that wine, lemon juice, grape juice, or vinegar was used as an acidic electrolyte solution to generate an electric current from the difference between the electrode potentials of the copper and iron electrodes.

König had observed a number of very fine silver objects from ancient Iraq, plated with very thin layers of gold, and speculated that they were electroplated using batteries with these as the cells.

Supporting experiments

After the Second World War, a man named Willard Gray demonstrated current production by a reconstruction of the inferred battery design when filled with grape juice. W. Jansen experimented with benzoquinone (some beetles produce quinones) and vinegar in a cell and got satisfactory performance.

In 1978, Arne Eggebrecht reportedly reproduced the electroplating of gold onto a small statue. There are no (direct) written or photographic records of this experiment. The only records are segments of a television show. (See "Media" below)

Refutation

Battery hypothesis

The artifacts do not form a useful voltaic for several reasons:

1. The copper tube is completely insulated at its "top": both from the iron bar and from the outside world, so there is no observable way for a circuit to be made
2. Gas is evolved at an iron/copper/electrolyte junction. Bubbles form a partial insulation of the electrode. Thus the more the battery is used, the less well it works.
3. Although several volts can be produced by connecting batteries in series, the voltage generated by iron/copper/electrolyte junctions is below 1 volt.

Electroplating hypothesis

König himself seems to have been mistaken on the nature of the objects he thought were electroplated. They were apparently fire-gilded (with mercury). Paul Craddock of the British Museum said "The examples we see from this region and era are conventional gold plating and mercury gilding. There’s never been any irrefutable evidence to support the electroplating theory".

David A. Scott, senior scientist at the Getty Conservation Institute and head of its Museum Research Laboratory, wrote that "There is a natural tendency for writers dealing with chemical technology to envisage these unique ancient objects of two thousand years ago as electroplating accessories (Foley 1977). but this is clearly untenable, for there is absolutely no evidence for electroplating in this region at the time."

Paul T. Keyser of the University of Alberta noted that Eggebrecht used a more efficient, modern electrolyte, and that using only vinegar, or other electrolytes available at the time assumed, the battery would be very feeble, and for that and other reasons concludes that even if this was in fact a battery, it could not have been used for electroplating. However, Keyser still supported the battery theory, but believed it was used for some kind of mild electrotherapy such as pain relief, possibly through electroacupuncture.

Bitumen as an insulator

A bitumen seal, being thermoplastic, would be extremely inconvenient for a galvanic cell, which would require frequent topping up of the electrolyte (if they were intended for extended use).

Alternative hypothesis

The artifacts strongly resemble another type of object with a known purpose – storage vessels for sacred scrolls from nearby Seleucia on the Tigris. Those vessels do not have the outermost clay jar, but are otherwise almost identical. Since these vessels were exposed to the elements, it is possible that any papyrus or parchment inside had completely rotted away, perhaps leaving a trace of slightly acidic organic residue. Likewise the thermoplastic bitumen makes an excellent hermetic seal for long-term storage.

In the media

The idea that the terracotta jars in certain circumstances could have been used to produce usable levels of electricity has been put to the test at least twice. On the 1980 British Television series Arthur C. Clarke's Mysterious World, Egyptologist Arne Eggebrecht created a voltaic cell using a jar filled with grape juice, to produce half a volt of electricity, demonstrating for the programme that jars used this way could electroplate a silver statuette in two hours, using a gold cyanide solution. Eggebrecht speculated that museums could contain many items mislabelled as gold when they are merely electroplated.

The Discovery Channel program MythBusters built replicas of the jars to see if it was indeed possible for them to have been used for electroplating or electrostimulation. On MythBusters' 29th episode (March 23, 2005), ten hand-made terracotta jars were fitted to act as batteries. Lemon juice was chosen as the electrolyte to activate the electrochemical reaction between the copper and iron. Connected in series, the batteries produced 4 volts of electricity. When linked in series the cells had sufficient power to electroplate a small token.

Archaeologist Ken Feder commented on the show noting that no archaeological evidence has been found either for connections between the jars (which were necessary to produce the required voltage) or for their use for electroplating. In fact, plating of the era in which the batteries are claimed to have been used, have been found to be fire-gilded (with mercury).

See also

• Dendera light
• Coso artifact - misinterpreted by some to be a 500,000-year-old spark plug
• History of the battery
• List of topics characterized as pseudoscience