Beryllium bromide

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Beryllium bromide
Beryllium bromide.svg
Names
IUPAC name
Beryllium bromide
Identifiers
7787-46-4 N
ChemSpider 74208 YesY
Jmol 3D model Interactive image
PubChem 82230
  • InChI=1S/Be.2BrH/h;2*1H/q+2;;/p-2 YesY
    Key: PBKYCFJFZMEFRS-UHFFFAOYSA-L YesY
  • InChI=1/Be.2BrH/h;2*1H/q+2;;/p-2
    Key: PBKYCFJFZMEFRS-NUQVWONBAJ
  • [Be+2].[Br-].[Br-]
Properties
BeBr2
Molar mass 168.820 g/mol
Appearance colorless white crystals
Density 3.465 g/cm3 (20 °C)
Melting point 508 °C (946 °F; 781 K)sublimes at 473 °C (883 °F; 746 K)
Boiling point 520 °C (968 °F; 793 K)[1]
Highly[1]
Solubility soluble in ethanol, diethyl ether, pyridine
insoluble in benzene
Structure
Orthorhombic
Thermochemistry
0.4111 J/g K
9.5395 J/K
-2.094 kJ/g
Vapor pressure {{{value}}}
Related compounds
Other anions
Beryllium fluoride
Beryllium chloride
Beryllium iodide
Other cations
Magnesium bromide
Calcium bromide
Strontium bromide
Barium bromide
Radium bromide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
N verify (what is YesYN ?)
Infobox references

Beryllium bromide is the chemical compound with the formula BeBr2. It is very hygroscopic and dissolves well in water. The compound is a polymer with tetrahedral Be centres.[2]

Preparation and reactions

It can be prepared by reacting beryllium metal with elemental bromine at temperatures of 500 °C to 700 °C:[1]

Be + Br2 → BeBr2

Beryllium bromide is also formed when treating beryllium oxide with hydrobromic acid:

BeO + 2 HBr → BeBr2 + H2O

It hydrolizes slowly in water: BeBr2 + 2 H2O → 2 HBr + Be(OH)2

Safety

Beryllium compounds are toxic if inhaled or ingested.

References

  1. 1.0 1.1 1.2 Lua error in package.lua at line 80: module 'strict' not found.
  2. Crystal modifications of Beryllium dihalides BeCl2, BeBr2, and BeI2 Troyanov, S. I. Zhurnal Neorganicheskoi Khimii (2000), 45(10), 1619-1624.


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