Copper(I) bromide

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Copper(I) bromide
Sample of copper(I) bromide
Structure of CuBr
Names
Other names
Cuprous bromide
Identifiers
7787-70-4 YesY
ChemSpider 22995 YesY
Jmol 3D model Interactive image
PubChem 24593
  • InChI=1S/BrH.Cu/h1H;/q;+1/p-1 YesY
    Key: NKNDPYCGAZPOFS-UHFFFAOYSA-M YesY
  • InChI=1/BrH.Cu/h1H;/q;+1/p-1
    Key: NKNDPYCGAZPOFS-REWHXWOFAY
  • Br[Cu]
Properties
CuBr
Molar mass 143.45 g/mol
Appearance green powder (see text)
Density 4.71 g/cm3, solid
Melting point 492 °C (918 °F; 765 K)
Boiling point 1,345 °C (2,453 °F; 1,618 K)
slightly soluble
Solubility soluble in HCl, HBr, ammonium hydroxide, acetonitrile
negligible in acetone, sulfuric acid
2.116
1.46 D
Vapor pressure {{{value}}}
Related compounds
Other anions
 Copper(I) chloride
Copper(I) iodide
Other cations
 Silver(I) bromide
Copper(II) bromide
Mercury(I) bromide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
YesY verify (what is YesYN ?)
Infobox references

Copper(I) bromide is the chemical compound with the formula CuBr. This diamagnetic solid adopts a polymeric structure akin to that for zinc sulfide. The compound is widely used in the synthesis of organic compounds.

Preparation, basic properties, structure

The pure solid is colourless, although samples are often colored due to the presence of copper(II) impurities (see picture).[1] The copper(I) ion also oxidizes easily in air. It is commonly prepared by the reduction of cupric salts with sulfite in the presence of bromide.[2] For example, the reduction of copper(II) bromide with sulfite yields copper(I) bromide and hydrogen bromide:

2 CuBr2 + H2O + SO32− → 2 CuBr + SO42− + 2 HBr

CuBr is insoluble in most solvents due to its polymeric structure, which features four-coordinated, tetrahedral Cu centers interconnected by bromide ligands (ZnS structure). Upon treatment with Lewis bases, CuBr converts to molecular adducts. For example with dimethyl sulfide, the colorless complex is formed:[3]

CuBr + S(CH3)2 → CuBr(S(CH3)2)

In this coordination complex, the copper is two-coordinate, with a linear geometry. Other soft ligands afford related complexes. For example triphenylphosphine gives CuBr(P(C6H5)3), although this species has a more complex structure. Thermal excitation of copper(I) bromide vapour yields a blue violet emission which is of greater saturation than known copper(I) chloride emission.[4] Copper(I) bromide is hence an advantageous emitter in pyrotechnic flames.

Applications in organic chemistry

In the Sandmeyer reaction, CuBr is employed to convert diazonium salts into the corresponding aryl bromides:[2]

ArN2+ + CuBr → ArBr + N2 + Cu+

The aforementioned complex CuBr(S(CH3)2) is widely used to generate organocopper reagents.[3] Related CuBr complexes are catalysts for Atom Transfer Radical Polymerization and Cu-catalyzed Cross-Dehydrogenative Couplings (CDC).

References

  1. ↑ Holleman, A. F.; Wiberg, E. "Inorganic Chemistry" Academic Press: San Diego, 2001. ISBN 0-12-352651-5.
  2. ↑ 2.0 2.1 This report gives a procedure for generating CuBr: Lua error in package.lua at line 80: module 'strict' not found.; Lua error in package.lua at line 80: module 'strict' not found..
  3. ↑ 3.0 3.1 Jarowicki, K.; Kocienski, P. J.; Qun, L. "1,2-Metallate Rearrangement: (Z)-4-(2-Propenyl)-3-Octen-1-ol" Organic Syntheses, Collected Volume 10, p.662 (2004).http://www.orgsyn.org/orgsyn/pdfs/V79P0011.pdf
  4. ↑ E.-C. Koch, Spectral Investigation and Color Properties of Copper(I) Halides CuX (X=F, Cl, Br, I) in Pyrotechnic Combustion Flames, Propellants Explos. Pyrotech. 2015, 40, 798-802.[1]

External links

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