Chrysanthemin

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Chrysanthemin
Cyanidin 3-O-glucoside.svg
Names
IUPAC name
(2S,3R,4S,5S,6R)-2-[2-(3,4-dihydroxyphenyl)-5,7-dihydroxychromenylium-3-yl]oxy-6-(hydroxymethyl)oxane-3,4,5-triol chloride
Other names
Chrysontenin
Glucocyanidin
Asterin
Chrysanthemin
Purple corn color
Kuromanin
Kuromanin chloride
Cyanidin 3-glucoside
Cyanidol 3-glucoside
Cyanidine 3-glucoside
Cyanidin 3-O-glucoside
cyanidin-3-O-beta-D-glucoside
Cyanidin 3-monoglucoside
Identifiers
7084-24-4 YesY
ChemSpider 170681 YesY
Jmol 3D model Interactive image
PubChem 197081
  • InChI=1S/C21H20O11.ClH/c22-7-16-17(27)18(28)19(29)21(32-16)31-15-6-10-12(25)4-9(23)5-14(10)30-20(15)8-1-2-11(24)13(26)3-8;/h1-6,16-19,21-22,27-29H,7H2,(H3-,23,24,25,26);1H/t16-,17-,18+,19-,21-;/m1./s1 YesY
    Key: YTMNONATNXDQJF-UBNZBFALSA-N YesY
  • InChI=1/C21H20O11.ClH/c22-7-16-17(27)18(28)19(29)21(32-16)31-15-6-10-12(25)4-9(23)5-14(10)30-20(15)8-1-2-11(24)13(26)3-8;/h1-6,16-19,21-22,27-29H,7H2,(H3-,23,24,25,26);1H/t16-,17-,18+,19-,21-;/m1./s1
    Key: YTMNONATNXDQJF-UBNZBFALBB
  • [Cl-].O(c1c([o+]c2c(c1)c(O)cc(O)c2)c3ccc(O)c(O)c3)[C@@H]4O[C@@H]([C@@H](O)[C@H](O)[C@H]4O)CO
Properties
C21H21O11+, Cl−
C21H21ClO11
Molar mass 484.83 g/mol (chloride)
449.38 g/mol
Vapor pressure {{{value}}}
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
YesY verify (what is YesYN ?)
Infobox references
UV visible spectrum of cyanidin 3-O-glucoside.

Chrysanthemin is an anthocyanin. It is the 3-glucoside of cyanidin.

Natural occurrences

Chrysanthemin can be found in the roselle plant (Hibiscus sabdariffa, Malvaceae), different Japanese angiosperms,[1] Rhaponticum (Asteraceae),[2] The fruits of the smooth arrowwood (Viburnum dentatum, Caprifoliaceae) appear blue. One of the major pigments is cyanidin 3-glucoside, but the total mixture is very complex.[3]

In food

Chrysanthemin has been detected in blackcurrant pomace, in European elderberry,[4] in red raspberries, in victoria plum,[5] in peach,[6] lychee and açaí.[7] It is found in red oranges.[8]

It is the major anthocyanin in purple corn (Zea mays). Purple corn is approved in Japan and listed in the "Existing Food Additive List" as purple corn color.[9]

Biosynthesis

The biosynthesis of cyanidin 3-O-glucoside in Escherichia coli was demonstrated by mean of metabolic genetic engineering.[10]

In Arabidopsis thaliana, a glycosyltransferase, UGT79B1, is involved in the anthocyanin biosynthetic pathway. UGT79B1 protein converts cyanidin 3-O-glucoside to cyanidin 3-O-xylosyl(1→2)glucoside.[11]

References

  1. ↑ "A survey of anthocyanins in sprouting leaves of some Japanese angiosperms studies on anthocyanins, LXV". Kunijiro Yoshitama, Makiko Ozaku, Michiko Hujii and Kôzô Hayashi, Journal of plant research, Volume 85, Number 4, pages 303–306, doi:10.1007/BF02490176
  2. ↑ "Chrysanthemin and cyanin in species of the genus Rhaponticum. V. V. Vereskovskii and I. I. Chekalinskaya, Chemistry of natural compounds, Volume 14, Number 4, pages 450–451, doi:10.1007/BF00565267
  3. ↑ "Food colorants: Anthocyanins". F. J. Francis and Pericles C. Markakis, Critical Reviews in Food Science and Nutrition, 1989, Volume 28, Issue 4, pages 273–314, doi:10.1080/10408398909527503
  4. ↑ Foods in which the polyphenol Cyanidin 3-O-glucoside is found, http://www.phenol-explorer.eu/contents/polyphenol/9
  5. ↑ The chemical constituents of victoria plums: Chrysanthemin, acid and pectin contents. D. Dickinson and Joy H. Gawler, Journal of the Science of Food and Agriculture, Volume 7, Issue 11, November 1956, pp. 699–705 doi:10.1002/jsfa.2740071103
  6. ↑ Postharvest sensory and phenolic characterization of 'Elegant Lady and 'Carson' peaches. Rodrigo Infante, Loreto Contador, Pía Rubio, Danilo Aros and Álvaro Peña-Neira, Chilean Journal Of Agricultural Research, 71(3), July–September 2011, pages 445–451 (article)
  7. ↑ Lua error in package.lua at line 80: module 'strict' not found.
  8. ↑ Influence of glucose on cyanidin 3-glucoside absorption in rats. Felgines C1, Texier O, Besson C, Vitaglione P, Lamaison JL, Fogliano V, Scalbert A, Vanella L and Galvano F, Mol Nutr Food Res., August 2008, volume 52, issue 8, pages 959-964, doi:10.1002/mnfr.200700377, Lua error in package.lua at line 80: module 'strict' not found.
  9. ↑ Anthocyanins isolated from purple corn (Zea mays L.). Hiromitsu Aoki, Noriko Kuze and Yoshiaki Kato (article)
  10. ↑ Lua error in package.lua at line 80: module 'strict' not found.
  11. ↑ "Two glycosyltransferases involved in anthocyanin modification delineated by transcriptome independent component analysis in Arabidopsis thaliana". Keiko Yonekura-Sakakibara, Atsushi Fukushima, Ryo Nakabayashi1, Kousuke Hanada, Fumio Matsuda, Satoko Sugawara, Eri Inoue, Takashi Kuromori, Takuya Ito, Kazuo Shinozaki, Bunyapa Wangwattana and Mami Yamazaki, The Plant Journal, 2012, volume 69, pages 154–167, doi:10.1111/j.1365-313X.2011.04779.x
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