The term greenhouse gas (sometimes abbreviated GHG) is used for a gas in an atmosphere that absorbs and emits radiation within the thermal infrared range. The theory of global warming and climate change relies on these gasses, particularly carbon dioxide, acting in the same role as the glass panes of a real greenhouse, absorbing the infrared energy from the heated ground, then re-emitting it back downwards, adding an extra component to the insulating, or blanketing, properties the air already has. This process is said to be the fundamental cause of the greenhouse effect. The primary infrared-absorbing and emitting gases in Earth's atmosphere are water vapor, carbon dioxide, methane, nitrous oxide, and ozone. In the Solar System, the atmospheres of Venus and Mars also contain carbon dioxide that is hypothesized to cause a greenhouse effect on those planets.
The "greenhouse effect" of gasses in the atmosphere is used to make an analogy with ordinary greenhouses, which get warmer in sunlight. The term is misapplied, because a real greenhouse gets warmer by physically trapping the heated air inside, not by re-radiation of infrared from the glass walls and roof. A greenhouse works by letting sunlight in, which warms the solid and liquid surfaces inside the structure. This heat energy is then transferred to the air inside the greenhouse. The heated air, which rises (convection), is prevented from leaving the greenhouse. The warmed air is physically trapped inside by the walls and roof of the greenhouse.
The explanation given for the warmer temperature in a real greenhouse, in many sources that promote the "radiative" greenhouse effect, is that incident solar radiation in the visible, long-wavelength ultraviolet, and short-wavelength infrared range of the spectrum passes through the glass roof and walls and is absorbed by the floor, earth, and contents, which become warmer and re-emit the energy as longer-wavelength infrared radiation. Glass and other materials used for greenhouse walls do not transmit infrared radiation, so the infrared cannot escape via radiative transfer, and so returns inside to heat the air and ground some more.
How a greenhouse actually works
The "greenhouse effect" of the atmosphere is named by analogy to greenhouses which get warmer in sunlight. The explanation given in most sources for the warmer temperature in an actual greenhouse is that incident solar radiation in the visible, long-wavelength ultraviolet, and short-wavelength infrared range of the spectrum passes through the glass roof and walls and is absorbed by the floor, earth, and contents, which become warmer and re-emit the energy as longer-wavelength infrared radiation. Glass and other materials used for greenhouse walls do not transmit infrared radiation, so the infrared cannot escape via radiative transfer. As the structure is not open to the atmosphere, heat also cannot escape via convection, so the temperature inside the greenhouse rises. The greenhouse effect, due to infrared-opaque "greenhouse gases" including carbon dioxide and methane instead of glass, also affects Earth as a whole; there is no convective cooling because no significant amount of air escapes from Earth.
However, a significant experiment shows that the mechanism by which the atmosphere retains heat—the "greenhouse effect"—is different; a greenhouse is not primarily warmed by the "greenhouse effect". A greenhouse works by allowing sunlight to warm solid and liquid surfaces inside the structure. This heat energy is then transferred to the air inside the greenhouse. The heated air, which rises, convection is prevented from leaving the greenhouse. It is trapped inside by the greenhouse glass.
A greenhouse is built of any transparent material that lets sunlight through, usually glass or plastic. It mainly warms up because the sun warms the ground and contents inside, which then warms the air in the greenhouse. The air continues to heat because it is confined within the greenhouse, unlike the environment outside the greenhouse where warm air near the surface rises and mixes with cooler air aloft. This can be demonstrated by opening a small window near the roof of a greenhouse: the temperature will drop considerably. It was demonstrated experimentally (R. W. Wood, 1909) that a "greenhouse" with a cover of rock salt (which is transparent to infra red) heats up an enclosure similarly to one with a glass cover. Thus greenhouses work primarily by preventing convective cooling.
In contrast, the greenhouse effect heats Earth because rather than retaining (sensible) heat by physically preventing movement of the air, greenhouse gases act to warm Earth by re-radiating some of the energy back towards the surface. This process may exist in real greenhouses, but is comparatively unimportant there.
Greenhouse gas concept used by global warming proponents
A greenhouse gas (sometimes abbreviated GHG) is a gas in an atmosphere that absorbs and emits radiation within the thermal infrared range. This process is the fundamental cause of the greenhouse effect. The primary greenhouse gases in Earth's atmosphere are water vapor, carbon dioxide, methane, nitrous oxide, and ozone.
The following statement needs fact checking. Two of the citations do not mention these numbers. The third, , is behind a paywall. Without greenhouse gases, the average temperature of Earth's surface would be about 15 °C (27 °F) colder than the present average of 14 °C.
The statement above may be referring to the blanketing, or insulation, effects of the atmosphere, regardless of any greenhouse gas.
Human activities since the beginning of the Industrial Revolution (taken to be the year 1750) have produced an estimated 40% increase in the atmospheric concentration of carbon dioxide, from an estimated 280 ppm in 1750 to 402 ppm in 2016.
This increase has occurred despite the uptake of a large portion of the emissions by various natural "sinks" involved in the carbon cycle. Anthropogenic carbon dioxide (CO2) emissions (i.e. emissions produced by human activities) come from combustion of carbon-based fuels, principally coal, oil, and natural gas, along with deforestation, soil erosion and animal agriculture.
By one estimate, if greenhouse gas emissions continue at the present rate, and if the climate models are accurate, Earth's surface temperature could exceed historical values as early as 2047, with potentially harmful, as well as beneficial, effects on ecosystems, biodiversity and the livelihoods of people worldwide.
- 1 How a greenhouse actually works
- 2 Greenhouse gas concept used by global warming proponents
- 3 Gases in Earth's atmosphere
- 4 Impacts on the overall greenhouse effect
- 5 Natural and anthropogenic sources
- 6 Anthropogenic greenhouse gases
- 7 Role of water vapor
- 8 Direct greenhouse gas emissions
- 8.1 Regional and national attribution of emissions
- 8.2 Land-use change
- 8.3 Greenhouse gas intensity
- 8.4 Cumulative and historical emissions
- 8.5 Changes since a particular base year
- 8.6 Annual emissions
- 8.7 Top emitter countries
- 8.8 Embedded emissions
- 8.9 Effect of policy
- 8.10 Projections
- 8.11 Relative CO2 emission from various fuels
- 9 Life-cycle greenhouse-gas emissions of energy sources
- 10 Removal from the atmosphere ("sinks")
- 11 History of scientific research
- 12 See also
- 13 References
- 14 Bibliography
- 15 External links
Gases in Earth's atmosphere
Greenhouse gases are those that absorb and emit infrared radiation in the wavelength range emitted by Earth. In order, the most abundant greenhouse gases in Earth's atmosphere are:
- Water vapor (H2O)
- Carbon dioxide (CO2)
- Methane (CH4)
- Nitrous oxide (N2O)
- Ozone (O3)
- Chlorofluorocarbons (CFCs)
Atmospheric concentrations of greenhouse gases are determined by the balance between sources (emissions of the gas from human activities and natural systems) and sinks (the removal of the gas from the atmosphere by conversion to a different chemical compound). The proportion of an emission remaining in the atmosphere after a specified time is the "airborne fraction" (AF). More precisely, the annual airborne fraction is the ratio of the atmospheric increase in a given year to that year's total emissions. Over the last 50 years (1956–2006) the airborne fraction for CO2 has been increasing at 0.25 ± 0.21%/year.
The major atmospheric constituents, nitrogen (N
2), oxygen (O
2), and argon (Ar), are not greenhouse gases. This is because molecules containing two atoms of the same element such as N
2 and O
2 and monatomic molecules such as argon (Ar) have no net change in the distribution of their electrical charges when they vibrate and hence are almost totally unaffected by infrared radiation. Although molecules containing two atoms of different elements such as carbon monoxide (CO) or hydrogen chloride (HCl) absorb infrared radiation, these molecules are short-lived in the atmosphere owing to their reactivity and solubility. Therefore, they do not contribute significantly to the greenhouse effect and usually are omitted when discussing greenhouse gases.
Indirect radiative effects
Some gases have indirect radiative effects (whether or not they are greenhouse gases themselves). This happens in two main ways. One way is that when they break down in the atmosphere they produce another greenhouse gas. For example, methane and carbon monoxide (CO) are oxidized to give carbon dioxide (and methane oxidation also produces water vapor; that will be considered below). Oxidation of CO to CO2 directly produces an unambiguous increase in radiative forcing although the reason is subtle. The peak of the thermal IR emission from Earth's surface is very close to a strong vibrational absorption band of CO2 (667 cm−1). On the other hand, the single CO vibrational band only absorbs IR at much higher frequencies (2145 cm−1), where the ~300 K thermal emission of the surface is at least a factor of ten lower. On the other hand, oxidation of methane to CO2, which requires reactions with the OH radical, produces an instantaneous reduction, since CO2 is a weaker greenhouse gas than methane; but it has a longer lifetime. As described below this is not the whole story, since the oxidations of CO and CH
4 are intertwined by both consuming OH radicals. In any case, the calculation of the total radiative effect needs to include both the direct and indirect forcing.
A second type of indirect effect happens when chemical reactions in the atmosphere involving these gases change the concentrations of greenhouse gases. For example, the destruction of non-methane volatile organic compounds (NMVOCs) in the atmosphere can produce ozone. The size of the indirect effect can depend strongly on where and when the gas is emitted.
Methane has a number of indirect effects in addition to forming CO2. Firstly, the main chemical that destroys methane in the atmosphere is the hydroxyl radical (OH). Methane reacts with OH and so more methane means that the concentration of OH goes down. Effectively, methane increases its own atmospheric lifetime and therefore its overall radiative effect. The second effect is that the oxidation of methane can produce ozone. Thirdly, as well as making CO2 the oxidation of methane produces water; this is a major source of water vapor in the stratosphere, which is otherwise very dry. CO and NMVOC also produce CO2 when they are oxidized. They remove OH from the atmosphere and this leads to higher concentrations of methane. The surprising effect of this is that the global warming potential of CO is three times that of CO2. The same process that converts NMVOC to carbon dioxide can also lead to the formation of tropospheric ozone. Halocarbons have an indirect effect because they destroy stratospheric ozone. Finally hydrogen can lead to ozone production and CH
4 increases as well as producing water vapor in the stratosphere.
Contribution of clouds to Earth's greenhouse effect
The major non-gas contributor to Earth's greenhouse effect, clouds, also absorb and emit infrared radiation and thus have an effect on radiative properties of the greenhouse gases. Clouds are water droplets or ice crystals suspended in the atmosphere.
Impacts on the overall greenhouse effect
The contribution of each gas to the greenhouse effect is affected by the characteristics of that gas, its abundance, and any indirect effects it may cause. For example, the direct radiative effect of a mass of methane is about 72 times stronger than the same mass of carbon dioxide over a 20-year time frame but it is present in much smaller concentrations so that its total direct radiative effect is smaller, in part due to its shorter atmospheric lifetime. On the other hand, in addition to its direct radiative impact, methane has a large, indirect radiative effect because it contributes to ozone formation. Shindell et al. (2005) argue that the contribution to climate change from methane is at least double previous estimates as a result of this effect.
When ranked by their direct contribution to the greenhouse effect, the most important are:
|Water vapor and clouds||H
(A) Water vapor strongly varies locally
In addition to the main greenhouse gases listed above, other greenhouse gases include sulfur hexafluoride, hydrofluorocarbons and perfluorocarbons (see IPCC list of greenhouse gases). Some greenhouse gases are not often listed. For example, nitrogen trifluoride has a high global warming potential (GWP) but is only present in very small quantities.
Proportion of direct effects at a given moment
It is not possible to state that a certain gas causes an exact percentage of the greenhouse effect. This is because some of the gases absorb and emit radiation at the same frequencies as others, so that the total greenhouse effect is not simply the sum of the influence of each gas. The higher ends of the ranges quoted are for each gas alone; the lower ends account for overlaps with the other gases. In addition, some gases such as methane are known to have large indirect effects that are still being quantified.
Aside from water vapor, which has a residence time of about nine days, major greenhouse gases are well mixed and take many years to leave the atmosphere. Although it is not easy to know with precision how long it takes greenhouse gases to leave the atmosphere, there are estimates for the principal greenhouse gases. Jacob (1999) defines the lifetime of an atmospheric species X in a one-box model as the average time that a molecule of X remains in the box. Mathematically can be defined as the ratio of the mass (in kg) of X in the box to its removal rate, which is the sum of the flow of X out of the box (), chemical loss of X (), and deposition of X () (all in kg/s): . If one stopped pouring any of this gas into the box, then after a time , its concentration would be about halved.
The atmospheric lifetime of a species therefore measures the time required to restore equilibrium following a sudden increase or decrease in its concentration in the atmosphere. Individual atoms or molecules may be lost or deposited to sinks such as the soil, the oceans and other waters, or vegetation and other biological systems, reducing the excess to background concentrations. The average time taken to achieve this is the mean lifetime.
Carbon dioxide has a variable atmospheric lifetime, and cannot be specified precisely. The atmospheric lifetime of CO2 is estimated of the order of 30–95 years. This figure accounts for CO2 molecules being removed from the atmosphere by mixing into the ocean, photosynthesis, and other processes. However, this excludes the balancing fluxes of CO2 into the atmosphere from the geological reservoirs, which have slower characteristic rates. Although more than half of the CO2 emitted is removed from the atmosphere within a century, some fraction (about 20%) of emitted CO2 remains in the atmosphere for many thousands of years.   Similar issues apply to other greenhouse gases, many of which have longer mean lifetimes than CO2. E.g., N2O has a mean atmospheric lifetime of 114 years.
Earth absorbs some of the radiant energy received from the sun, reflects some of it as light and reflects or radiates the rest back to space as heat. Earth's surface temperature depends on this balance between incoming and outgoing energy. If this energy balance is shifted, Earth's surface could become warmer or cooler, leading to a variety of changes in global climate.
A number of natural and man-made mechanisms can affect the global energy balance and force changes in Earth's climate. Greenhouse gases are one such mechanism. Greenhouse gases in the atmosphere absorb and re-emit some of the outgoing energy radiated from Earth's surface, causing that heat to be retained in the lower atmosphere. As explained above, some greenhouse gases remain in the atmosphere for decades or even centuries, and therefore can affect Earth's energy balance over a long time period. Factors that influence Earth's energy balance can be quantified in terms of "radiative climate forcing." Positive radiative forcing indicates warming (for example, by increasing incoming energy or decreasing the amount of energy that escapes to space), whereas negative forcing is associated with cooling.
Global warming potential
The global warming potential (GWP) depends on both the efficiency of the molecule as a greenhouse gas and its atmospheric lifetime. GWP is measured relative to the same mass of CO2 and evaluated for a specific timescale. Thus, if a gas has a high (positive) radiative forcing but also a short lifetime, it will have a large GWP on a 20-year scale but a small one on a 100-year scale. Conversely, if a molecule has a longer atmospheric lifetime than CO2 its GWP will increase with the timescale considered. Carbon dioxide is defined to have a GWP of 1 over all time periods.
Methane has an atmospheric lifetime of 12 ± 3 years. The 2007 IPCC report lists the GWP as 72 over a time scale of 20 years, 25 over 100 years and 7.6 over 500 years. A 2014 analysis, however, states that although methane's initial impact is about 100 times greater than that of CO2, because of the shorter atmospheric lifetime, after six or seven decades, the impact of the two gases is about equal, and from then on methane's relative role continues to decline. The decrease in GWP at longer times is because methane is degraded to water and CO2 through chemical reactions in the atmosphere.
|Global warming potential (GWP) for given time horizon|
|100||11 000||10 900||5 200|
|12||5 160||1 810||549|
|50 000||5 210||7 390||11 200|
|10 000||8 630||12 200||18 200|
|3 200||16 300||22 800||32 600|
|740||12 300||17 200||20 700|
Natural and anthropogenic sources
Aside from purely human-produced synthetic halocarbons, most greenhouse gases have both natural and human-caused sources. During the pre-industrial Holocene, concentrations of existing gases were roughly constant. In the industrial era, human activities have added greenhouse gases to the atmosphere, mainly through the burning of fossil fuels and clearing of forests.
The 2007 Fourth Assessment Report compiled by the IPCC (AR4) noted that "changes in atmospheric concentrations of greenhouse gases and aerosols, land cover and solar radiation alter the energy balance of the climate system", and concluded that "increases in anthropogenic greenhouse gas concentrations is very likely to have caused most of the increases in global average temperatures since the mid-20th century". In AR4, "most of" is defined as more than 50%.
|Carbon dioxide (CO2)||280 ppm||395.4 ppm||115.4 ppm||41.2%||1.88|
|700 ppb||1893 ppb /
|1193 ppb /
|Nitrous oxide (N
|270 ppb||326 ppb /
|56 ppb /
|237 ppb||337 ppb||100 ppb||42%||0.4|
|236 ppt /
|527 ppt /
|74 ppt /
|231 ppt /
|24 ppt /
|23 ppt /
|Halon 1211 (CBrClF
|4.1 ppt /
|Halon 1301 (CBrClF
|3.3 ppt /
|75 ppt /
|Carbon tetrachloride (CCl
|85 ppt /
|Sulfur hexafluoride (SF
|7.79 ppt /
|Other halocarbons||Varies by
|Halocarbons in total||0.3574|
Ice cores provide evidence for greenhouse gas concentration variations over the past 800,000 years (see the following section). Both CO2 and CH
4 vary between glacial and interglacial phases, and concentrations of these gases correlate strongly with temperature. Direct data does not exist for periods earlier than those represented in the ice core record, a record that indicates CO2 mole fractions stayed within a range of 180 ppm to 280 ppm throughout the last 800,000 years, until the increase of the last 250 years. However, various proxies and modeling suggests larger variations in past epochs; 500 million years ago CO2 levels were likely 10 times higher than now. Indeed, higher CO2 concentrations are thought to have prevailed throughout most of the Phanerozoic eon, with concentrations four to six times current concentrations during the Mesozoic era, and ten to fifteen times current concentrations during the early Palaeozoic era until the middle of the Devonian period, about 400 Ma. The spread of land plants is thought to have reduced CO2 concentrations during the late Devonian, and plant activities as both sources and sinks of CO2 have since been important in providing stabilising feedbacks. Earlier still, a 200-million year period of intermittent, widespread glaciation extending close to the equator (Snowball Earth) appears to have been ended suddenly, about 550 Ma, by a colossal volcanic outgassing that raised the CO2 concentration of the atmosphere abruptly to 12%, about 350 times modern levels, causing extreme greenhouse conditions and carbonate deposition as limestone at the rate of about 1 mm per day. This episode marked the close of the Precambrian eon, and was succeeded by the generally warmer conditions of the Phanerozoic, during which multicellular animal and plant life evolved. No volcanic carbon dioxide emission of comparable scale has occurred since. In the modern era, emissions to the atmosphere from volcanoes are only about 1% of emissions from human sources.
Measurements from Antarctic ice cores show that before industrial emissions started atmospheric CO2 mole fractions were about 280 parts per million (ppm), and stayed between 260 and 280 during the preceding ten thousand years. Carbon dioxide mole fractions in the atmosphere have gone up by approximately 35 percent since the 1900s, rising from 280 parts per million by volume to 387 parts per million in 2009. One study using evidence from stomata of fossilized leaves suggests greater variability, with carbon dioxide mole fractions above 300 ppm during the period seven to ten thousand years ago, though others have argued that these findings more likely reflect calibration or contamination problems rather than actual CO2 variability. Because of the way air is trapped in ice (pores in the ice close off slowly to form bubbles deep within the firn) and the time period represented in each ice sample analyzed, these figures represent averages of atmospheric concentrations of up to a few centuries rather than annual or decadal levels.
Changes since the Industrial Revolution
Since the beginning of the Industrial Revolution, the concentrations of most of the greenhouse gases have increased. For example, the mole fraction of carbon dioxide has increased from 280 ppm by about 36% to 380 ppm, or 100 ppm over modern pre-industrial levels. The first 50 ppm increase took place in about 200 years, from the start of the Industrial Revolution to around 1973.; however the next 50 ppm increase took place in about 33 years, from 1973 to 2006.
Recent data also shows that the concentration is increasing at a higher rate. In the 1960s, the average annual increase was only 37% of what it was in 2000 through 2007.
Today, the stock of carbon in the atmosphere increases by more than 3 million tonnes per annum (0.04%) compared with the existing stock.[clarification needed] This increase is the result of human activities by burning fossil fuels, deforestation and forest degradation in tropical and boreal regions.
The other greenhouse gases produced from human activity show similar increases in both amount and rate of increase. Many observations are available online in a variety of Atmospheric Chemistry Observational Databases.
Anthropogenic greenhouse gases
Since about 1750 human activity has increased the concentration of carbon dioxide and other greenhouse gases. Measured atmospheric concentrations of carbon dioxide are currently 100 ppm higher than pre-industrial levels. Natural sources of carbon dioxide are more than 20 times greater than sources due to human activity, but over periods longer than a few years natural sources are closely balanced by natural sinks, mainly photosynthesis of carbon compounds by plants and marine plankton. As a result of this balance, the atmospheric mole fraction of carbon dioxide remained between 260 and 280 parts per million for the 10,000 years between the end of the last glacial maximum and the start of the industrial era.
It is likely that anthropogenic (i.e., human-induced) warming, such as that due to elevated greenhouse gas levels, has had a discernible influence on many physical and biological systems. Future warming is projected to have a range of impacts, including sea level rise, increased frequencies and severities of some extreme weather events, loss of biodiversity, and regional changes in agricultural productivity.
The main sources of greenhouse gases due to human activity are:
- burning of fossil fuels and deforestation leading to higher carbon dioxide concentrations in the air. Land use change (mainly deforestation in the tropics) account for up to one third of total anthropogenic CO2 emissions.
- livestock enteric fermentation and manure management, paddy rice farming, land use and wetland changes, pipeline losses, and covered vented landfill emissions leading to higher methane atmospheric concentrations. Many of the newer style fully vented septic systems that enhance and target the fermentation process also are sources of atmospheric methane.
- use of chlorofluorocarbons (CFCs) in refrigeration systems, and use of CFCs and halons in fire suppression systems and manufacturing processes.
- agricultural activities, including the use of fertilizers, that lead to higher nitrous oxide (N
The seven sources of CO2 from fossil fuel combustion are (with percentage contributions for 2000–2004):
|Seven main fossil fuel
|Liquid fuels (e.g., gasoline, fuel oil)||36%|
|Solid fuels (e.g., coal)||35%|
|Gaseous fuels (e.g., natural gas)||20%|
|Cement production||3 %|
|Flaring gas industrially and at wells||< 1%|
|Non-fuel hydrocarbons||< 1%|
|"International bunker fuels" of transport
not included in national inventories
Carbon dioxide, methane, nitrous oxide (N
2O) and three groups of fluorinated gases (sulfur hexafluoride (SF
6), hydrofluorocarbons (HFCs), and perfluorocarbons (PFCs)) are the major anthropogenic greenhouse gases,:147 and are regulated under the Kyoto Protocol international treaty, which came into force in 2005. Emissions limitations specified in the Kyoto Protocol expired in 2012. The Cancún agreement, agreed in 2010, includes voluntary pledges made by 76 countries to control emissions. At the time of the agreement, these 76 countries were collectively responsible for 85% of annual global emissions.
Although CFCs are greenhouse gases, they are regulated by the Montreal Protocol, which was motivated by CFCs' contribution to ozone depletion rather than by their contribution to global warming. Note that ozone depletion has only a minor role in greenhouse warming though the two processes often are confused in the media.
|This section requires expansion with: Information on emissions from other sectors. (July 2013)|
According to UNEP global tourism is closely linked to climate change. Tourism is a significant contributor to the increasing concentrations of greenhouse gases in the atmosphere. Tourism accounts for about 50% of traffic movements. Rapidly expanding air traffic contributes about 2.5% of the production of CO2. The number of international travelers is expected to increase from 594 million in 1996 to 1.6 billion by 2020, adding greatly to the problem unless steps are taken to reduce emissions.
The road haulage industry plays a part in production of CO2, contributing around 20% of the UK’s total carbon emissions a year, with only the energy industry having a larger impact at around 39%. Average carbon emissions within the haulage industry are falling—in the thirty-year period from 1977–2007, the carbon emissions associated with a 200-mile journey fell by 21 percent; NOx emissions are also down 87 percent, whereas journey times have fallen by around a third. Due to their size, HGVs often receive criticism regarding their CO2 emissions; however, rapid development in engine technology and fuel management is having a largely positive effect.
Role of water vapor
Water vapor accounts for the largest percentage of the greenhouse effect, between 36% and 66% for clear sky conditions and between 66% and 85% when including clouds. Water vapor concentrations fluctuate regionally, but human activity does not significantly affect water vapor concentrations except at local scales, such as near irrigated fields. The atmospheric concentration of vapor is highly variable and depends largely on temperature, from less than 0.01% in extremely cold regions up to 3% by mass at in saturated air at about 32 °C. (See Relative humidity#other important facts.)
The average residence time of a water molecule in the atmosphere is only about nine days, compared to years or centuries for other greenhouse gases such as CH
4 and CO2. Thus, water vapor responds to and amplifies effects of the other greenhouse gases. The Clausius–Clapeyron relation establishes that more water vapor will be present per unit volume at elevated temperatures. This and other basic principles indicate that warming associated with increased concentrations of the other greenhouse gases also will increase the concentration of water vapor (assuming that the relative humidity remains approximately constant; modeling and observational studies find that this is indeed so). Because water vapor is a greenhouse gas, this results in further warming and so is a "positive feedback" that amplifies the original warming. Eventually other earth processes offset these positive feedbacks, stabilizing the global temperature at a new equilibrium and preventing the loss of Earth's water through a Venus-like runaway greenhouse effect.
Direct greenhouse gas emissions
Between the period 1970 to 2004, GHG emissions (measured in CO2-equivalent) increased at an average rate of 1.6% per year, with CO2 emissions from the use of fossil fuels growing at a rate of 1.9% per year. Total anthropogenic emissions at the end of 2009 were estimated at 49.5 gigatonnes CO2-equivalent.:15 These emissions include CO2 from fossil fuel use and from land use, as well as emissions of methane, nitrous oxide and other GHGs covered by the Kyoto Protocol.
Regional and national attribution of emissions
- Definition of measurement boundaries: Emissions can be attributed geographically, to the area where they were emitted (the territory principle) or by the activity principle to the territory produced the emissions. These two principles result in different totals when measuring, for example, electricity importation from one country to another, or emissions at an international airport.
- Time horizon of different GHGs: Contribution of a given GHG is reported as a CO2 equivalent. The calculation to determine this takes into account how long that gas remains in the atmosphere. This is not always known accurately and calculations must be regularly updated to reflect new information.
- What sectors are included in the calculation (e.g., energy industries, industrial processes, agriculture etc.): There is often a conflict between transparency and availability of data.
- The measurement protocol itself: This may be via direct measurement or estimation. The four main methods are the emission factor-based method, mass balance method, predictive emissions monitoring systems, and continuous emissions monitoring systems. These methods differ in accuracy, cost, and usability.
These different measures are sometimes used by different countries to assert various policy/ethical positions on climate change (Banuri et al., 1996, p. 94). This use of different measures leads to a lack of comparability, which is problematic when monitoring progress towards targets. There are arguments for the adoption of a common measurement tool, or at least the development of communication between different tools.
Emissions may be measured over long time periods. This measurement type is called historical or cumulative emissions. Cumulative emissions give some indication of who is responsible for the build-up in the atmospheric concentration of GHGs (IEA, 2007, p. 199).
The national accounts balance would be positively related to carbon emissions. The national accounts balance shows the difference between exports and imports. For many richer nations, such as the United States, the accounts balance is negative because more goods are imported than they are exported. This is mostly due to the fact that it is cheaper to produce goods outside of developed countries, leading the economies of developed countries to become increasingly dependent on services and not goods. We believed that a positive accounts balance would means that more production was occurring in a country, so more factories working would increase carbon emission levels.(Holtz-Eakin, 1995, pp.;85;101).
Emissions may also be measured across shorter time periods. Emissions changes may, for example, be measured against a base year of 1990. 1990 was used in the United Nations Framework Convention on Climate Change (UNFCCC) as the base year for emissions, and is also used in the Kyoto Protocol (some gases are also measured from the year 1995).:146,149 A country's emissions may also be reported as a proportion of global emissions for a particular year.
Another measurement is of per capita emissions. This divides a country's total annual emissions by its mid-year population.:370 Per capita emissions may be based on historical or annual emissions (Banuri et al., 1996, pp. 106–107).
Land-use change, e.g., the clearing of forests for agricultural use, can affect the concentration of GHGs in the atmosphere by altering how much carbon flows out of the atmosphere into carbon sinks. Accounting for land-use change can be understood as an attempt to measure "net" emissions, i.e., gross emissions from all GHG sources minus the removal of emissions from the atmosphere by carbon sinks (Banuri et al., 1996, pp. 92–93).
There are substantial uncertainties in the measurement of net carbon emissions. Additionally, there is controversy over how carbon sinks should be allocated between different regions and over time (Banuri et al., 1996, p. 93). For instance, concentrating on more recent changes in carbon sinks is likely to favour those regions that have deforested earlier, e.g., Europe.
Greenhouse gas intensity
Greenhouse gas intensity is a ratio between greenhouse gas emissions and another metric, e.g., gross domestic product (GDP) or energy use. The terms "carbon intensity" and "emissions intensity" are also sometimes used. GHG intensities may be calculated using market exchange rates (MER) or purchasing power parity (PPP) (Banuri et al., 1996, p. 96). Calculations based on MER show large differences in intensities between developed and developing countries, whereas calculations based on PPP show smaller differences.
Cumulative and historical emissions
Cumulative anthropogenic (i.e., human-emitted) emissions of CO2 from fossil fuel use are a major cause of global warming, and give some indication of which countries have contributed most to human-induced climate change.:15
|OECD North America||33.2||29.7|
The table above to the left is based on Banuri et al. (1996, p. 94). Overall, developed countries accounted for 83.8% of industrial CO2 emissions over this time period, and 67.8% of total CO2 emissions. Developing countries accounted for industrial CO2 emissions of 16.2% over this time period, and 32.2% of total CO2 emissions. The estimate of total CO2 emissions includes biotic carbon emissions, mainly from deforestation. Banuri et al. (1996, p. 94) calculated per capita cumulative emissions based on then-current population. The ratio in per capita emissions between industrialized countries and developing countries was estimated at more than 10 to 1.
Including biotic emissions brings about the same controversy mentioned earlier regarding carbon sinks and land-use change (Banuri et al., 1996, pp. 93–94). The actual calculation of net emissions is very complex, and is affected by how carbon sinks are allocated between regions and the dynamics of the climate system.
Non-OECD countries accounted for 42% of cumulative energy-related CO2 emissions between 1890–2007.:179–180 Over this time period, the US accounted for 28% of emissions; the EU, 23%; Russia, 11%; China, 9%; other OECD countries, 5%; Japan, 4%; India, 3%; and the rest of the world, 18%.:179–180
Changes since a particular base year
Between 1970–2004, global growth in annual CO2 emissions was driven by North America, Asia, and the Middle East. The sharp acceleration in CO2 emissions since 2000 to more than a 3% increase per year (more than 2 ppm per year) from 1.1% per year during the 1990s is attributable to the lapse of formerly declining trends in carbon intensity of both developing and developed nations. China was responsible for most of global growth in emissions during this period. Localised plummeting emissions associated with the collapse of the Soviet Union have been followed by slow emissions growth in this region due to more efficient energy use, made necessary by the increasing proportion of it that is exported. In comparison, methane has not increased appreciably, and N
2O by 0.25% y−1.
Using different base years for measuring emissions has an effect on estimates of national contributions to global warming.:17–18 This can be calculated by dividing a country's highest contribution to global warming starting from a particular base year, by that country's minimum contribution to global warming starting from a particular base year. Choosing between different base years of 1750, 1900, 1950, and 1990 has a significant effect for most countries.:17–18 Within the G8 group of countries, it is most significant for the UK, France and Germany. These countries have a long history of CO2 emissions (see the section on Cumulative and historical emissions).
Annual per capita emissions in the industrialized countries are typically as much as ten times the average in developing countries.:144 Due to China's fast economic development, its annual per capita emissions are quickly approaching the levels of those in the Annex I group of the Kyoto Protocol (i.e., the developed countries excluding the USA). Other countries with fast growing emissions are South Korea, Iran, and Australia (which apart from the oil rich Persian Gulf states, now has the highest percapita emission rate in the world). On the other hand, annual per capita emissions of the EU-15 and the USA are gradually decreasing over time. Emissions in Russia and the Ukraine have decreased fastest since 1990 due to economic restructuring in these countries.
Energy statistics for fast growing economies are less accurate than those for the industrialized countries. For China's annual emissions in 2008, the Netherlands Environmental Assessment Agency estimated an uncertainty range of about 10%.
The GHG footprint, or greenhouse gas footprint, refers to the amount of GHG that are emitted during the creation of products or services. It is more comprehensive than the commonly used carbon footprint, which measures only carbon dioxide, one of many greenhouse gases.
2015 was the first year to see both total global economic growth and a reduction of carbon emissions.
Top emitter countries
In 2009, the annual top ten emitting countries accounted for about two-thirds of the world's annual energy-related CO2 emissions.
|Country|| % of global total
|Tonnes of GHG
|People's Rep. of China||23.6||5.13|
|Islamic Rep. of Iran||1.8||7.3|
|Country|| % of world
CO2 per person
One way of attributing greenhouse gas (GHG) emissions is to measure the embedded emissions (also referred to as "embodied emissions") of goods that are being consumed. Emissions are usually measured according to production, rather than consumption. For example, in the main international treaty on climate change (the UNFCCC), countries report on emissions produced within their borders, e.g., the emissions produced from burning fossil fuels.:179:1 Under a production-based accounting of emissions, embedded emissions on imported goods are attributed to the exporting, rather than the importing, country. Under a consumption-based accounting of emissions, embedded emissions on imported goods are attributed to the importing country, rather than the exporting, country.
Davis and Caldeira (2010):4 found that a substantial proportion of CO2 emissions are traded internationally. The net effect of trade was to export emissions from China and other emerging markets to consumers in the US, Japan, and Western Europe. Based on annual emissions data from the year 2004, and on a per-capita consumption basis, the top-5 emitting countries were found to be (in tCO2 per person, per year): Luxembourg (34.7), the US (22.0), Singapore (20.2), Australia (16.7), and Canada (16.6).:5 Carbon Trust research revealed that approximately 25% of all CO2 emissions from human activities 'flow' (i.e. are imported or exported) from one country to another. Major developed economies were found to be typically net importers of embodied carbon emissions — with UK consumption emissions 34% higher than production emissions, and Germany (29%), Japan (19%) and the USA (13%) also significant net importers of embodied emissions.
Effect of policy
Governments have taken action to reduce GHG emissions (climate change mitigation). Assessments of policy effectiveness have included work by the Intergovernmental Panel on Climate Change, International Energy Agency, and United Nations Environment Programme. Policies implemented by governments have included national and regional targets to reduce emissions, promoting energy efficiency, and support for renewable energy such as Solar energy as an effective use of renewable energy because solar uses energy from the sun and does not release pollutants into the air.
Countries and regions listed in Annex I of the United Nations Framework Convention on Climate Change (UNFCCC) (i.e., the OECD and former planned economies of the Soviet Union) are required to submit periodic assessments to the UNFCCC of actions they are taking to address climate change.:3 Analysis by the UNFCCC (2011):8 suggested that policies and measures undertaken by Annex I Parties may have produced emission savings of 1.5 thousand Tg CO2-eq in the year 2010, with most savings made in the energy sector. The projected emissions saving of 1.5 thousand Tg CO2-eq is measured against a hypothetical "baseline" of Annex I emissions, i.e., projected Annex I emissions in the absence of policies and measures. The total projected Annex I saving of 1.5 thousand CO2-eq does not include emissions savings in seven of the Annex I Parties.:8
A wide range of projections of future GHG emissions have been produced. Rogner et al. (2007) assessed the scientific literature on GHG projections. Rogner et al. (2007) concluded that unless energy policies changed substantially, the world would continue to depend on fossil fuels until 2025–2030. Projections suggest that more than 80% of the world's energy will come from fossil fuels. This conclusion was based on "much evidence" and "high agreement" in the literature. Projected annual energy-related CO2 emissions in 2030 were 40–110% higher than in 2000, with two-thirds of the increase originating in developing countries. Projected annual per capita emissions in developed country regions remained substantially lower (2.8–5.1 tonnes CO2) than those in developed country regions (9.6–15.1 tonnes CO2). Projections consistently showed increase in annual world GHG emissions (the "Kyoto" gases, measured in CO2-equivalent) of 25–90% by 2030, compared to 2000.
Relative CO2 emission from various fuels
One liter of gasoline, when used as a fuel, produces 2.32 kg (about 1300 liters or 1.3 cubic meters) of carbon dioxide, a greenhouse gas. One US gallon produces 19.4 lb (1,291.5 gallons or 172.65 cubic feet)
|Liquefied petroleum gas||139||59.76|
|Tires/tire derived fuel||189||81.26|
|Wood and wood waste||195||83.83|
|Tar-sand Bitumen|||||
Life-cycle greenhouse-gas emissions of energy sources
A literature review of numerous energy sources CO2 emissions by the IPCC in 2011, found that, the CO2 emission value that fell within the 50th percentile of all total life cycle emissions studies conducted was as follows.
|Ocean Energy||wave and tidal||8|
|Nuclear||various generation II reactor types||16|
|Solar thermal||parabolic trough||22|
|Geothermal||hot dry rock||45|
|Solar PV||Polycrystalline silicon||46|
|Natural gas||various combined cycle turbines without scrubbing||469|
|Coal||various generator types without scrubbing||1001|
Removal from the atmosphere ("sinks")
Greenhouse gases can be removed from the atmosphere by various processes, as a consequence of:
- a physical change (condensation and precipitation remove water vapor from the atmosphere).
- a chemical reaction within the atmosphere. For example, methane is oxidized by reaction with naturally occurring hydroxyl radical, OH• and degraded to CO2 and water vapor (CO2 from the oxidation of methane is not included in the methane Global warming potential). Other chemical reactions include solution and solid phase chemistry occurring in atmospheric aerosols.
- a physical exchange between the atmosphere and the other compartments of the planet. An example is the mixing of atmospheric gases into the oceans.
- a chemical change at the interface between the atmosphere and the other compartments of the planet. This is the case for CO2, which is reduced by photosynthesis of plants, and which, after dissolving in the oceans, reacts to form carbonic acid and bicarbonate and carbonate ions (see ocean acidification).
- a photochemical change. Halocarbons are dissociated by UV light releasing Cl• and F• as free radicals in the stratosphere with harmful effects on ozone (halocarbons are generally too stable to disappear by chemical reaction in the atmosphere).
A number of technologies remove greenhouse gases emissions from the atmosphere. Most widely analysed are those that remove carbon dioxide from the atmosphere, either to geologic formations such as bio-energy with carbon capture and storage and carbon dioxide air capture, or to the soil as in the case with biochar. The IPCC has pointed out that many long-term climate scenario models require large scale manmade negative emissions to avoid serious climate change.
History of scientific research
In the late 19th century scientists experimentally discovered that N2 and O2 do not absorb infrared radiation (called, at that time, "dark radiation"), while water (both as true vapor and condensed in the form of microscopic droplets suspended in clouds) and CO2 and other poly-atomic gaseous molecules do absorb infrared radiation. In the early 20th century researchers realized that greenhouse gases in the atmosphere made Earth's overall temperature higher than it would be without them. During the late 20th century, an hypothesis was put forth that increasing concentrations of what are called greenhouse gases in the atmosphere cause a substantial rise in global temperatures and changes to other parts of the climate system, with consequences for the environment and for human health.
- Attribution of recent climate change
- Carbon accounting
- Carbon credit
- Carbon emissions reporting
- Carbon neutrality
- Carbon offset
- Cap and Trade
- Deforestation and climate change
- Effects of global warming
- Emission standard
- Environmental impact of aviation
- Greenhouse debt
- Hydrogen economy
- Integrated Carbon Observation System
- List of countries by electricity production from renewable sources
- List of international environmental agreements
- Low-carbon economy
- Mobile source air pollution
- Physical properties of greenhouse gases
- Sustainability measurement
- World energy consumption
- Zero-emissions vehicle
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When exposed to sunlight the temperature rose gradually to 65 °C., the enclosure covered with the salt plate keeping a little ahead of the other because it transmitted the longer waves from the Sun, which were stopped by the glass. In order to eliminate this action the sunlight was first passed through a glass plate." "it is clear that the rock-salt plate is capable of transmitting practically all of it, while the glass plate stops it entirely. This shows us that the loss of temperature of the ground by radiation is very small in comparison to the loss by convection, in other words that we gain very little from the circumstance that the radiation is trapped.
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... this mechanism is called the greenhouse effect, even though most greenhouses depend primarily on a different mechanism (namely, limiting convective cooling).
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- Ehhalt, D.; et al., "Ch 4. Atmospheric Chemistry and Greenhouse Gases", Table 4.1, in IPCC TAR WG1 2001, pp. 244–245. Referred to by: Blasing, T. J. (February 2013), Current Greenhouse Gas Concentrations, doi:10.3334/CDIAC/atg.032, on CDIAC 2013. Based on Blasing et al. (2013): Pre-1750 concentrations of CH4,N2O and current concentrations of O3, are taken from Table 4.1 (a) of the IPCC Intergovernmental Panel on Climate Change), 2001. Following the convention of IPCC (2001), inferred global-scale trace-gas concentrations from prior to 1750 are assumed to be practically uninfluenced by human activities such as increasingly specialized agriculture, land clearing, and combustion of fossil fuels. Preindustrial concentrations of industrially manufactured compounds are given as zero. The short atmospheric lifetime of ozone (hours-days) together with the spatial variability of its sources precludes a globally or vertically homogeneous distribution, so that a fractional unit such as parts per billion would not apply over a range of altitudes or geographical locations. Therefore a different unit is used to integrate the varying concentrations of ozone in the vertical dimension over a unit area, and the results can then be averaged globally. This unit is called a Dobson Unit (D.U.), after G. M. B. Dobson, one of the first investigators of atmospheric ozone. A Dobson unit is the amount of ozone in a column that, unmixed with the rest of the atmosphere, would be 10 micrometers thick at standard temperature and pressure.
- Because atmospheric concentrations of most gases tend to vary systematically over the course of a year, figures given represent averages over a 12-month period for all gases except ozone (O3), for which a current global value has been estimated (IPCC, 2001, Table 4.1a). CO2 averages for year 2012 are taken from the National Oceanic and Atmospheric Administration, Earth System Research Laboratory, web site: www.esrl.noaa.gov/gmd/ccgg/trends maintained by Dr. Pieter Tans. For other chemical species, the values given are averages for 2011. These data are found on the CDIAC AGAGE web site: http://cdiac.ornl.gov/ndps/alegage.html or the AGAGE home page: http://agage.eas.gatech.edu.
- Forster, P.; et al., "Ch 2: Changes in Atmospheric Constituents and in Radiative Forcing", Table 2.1, in IPCC AR4 WG1 2007, p. 141. Referred to by: Blasing, T. J. (February 2013), Current Greenhouse Gas Concentrations, doi:10.3334/CDIAC/atg.032, on CDIAC 2013. For the latest updates, see the NOAA Annual Greenhouse Gas Index at: .
- Prentice, I. C.; et al., "Ch 3. The Carbon Cycle and Atmospheric Carbon Dioxide", Executive summary, in IPCC TAR WG1 2001, p. 185. Referred to by: Blasing, T. J. (February 2013), Current Greenhouse Gas Concentrations, doi:10.3334/CDIAC/atg.032, on CDIAC 2013
- Recent CO2 concentration (395.4 ppm) is the 2013 average taken from globally averaged marine surface data given by the National Oceanic and Atmospheric Administration Earth System Research Laboratory, website: http://www.esrl.noaa.gov/gmd/ccgg/trends/index.html#global. Please read the material on that web page and reference Dr. Pieter Tans when citing this average (Dr. Pieter Tans, NOAA/ESRL http://www.esrl.noaa.gov/gmd/ccgg/trends). The oft-cited Mauna Loa average for 2012 is 393.8 ppm, which is a good approximation although typically about 1 ppm higher than the spatial average given above. Refer to http://www.esrl.noaa.gov/gmd/ccgg/trends for records back to the late 1950s.
- ppb = parts-per-billion
- The first value in a cell represents Mace Head, Ireland, a mid-latitude Northern-Hemisphere site, and the second value represents Cape Grim, Tasmania, a mid-latitude Southern-Hemisphere site. "Current" values given for these gases are annual arithmetic averages based on monthly background concentrations for year 2011. The SF
6 values are from the AGAGE gas chromatography – mass spectrometer (gc-ms) Medusa measuring system. Source: Advanced Global Atmospheric Gases Experiment (AGAGE) data posted on CDIAC web site at: http://cdiac.ornl.gov/ftp/ale_gage_Agage/. These data are compiled from data on finer time scales in the ALE/GAGE/AGAGE database  (Prinn et al., 2000). These data represent the work of several investigators at various institutions; guidelines on citing the various parts of the AGAGE database are found within the ALE/GAGE/AGAGE database, see: .
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2O is consistent with ice-core records from 10,000 B.C.E. through 1750 C.E.: "Summary for policymakers", Figure SPM.1, IPCC, in IPCC AR4 WG1 2007, p. 3. Referred to by: Blasing, T. J. (February 2013), Current Greenhouse Gas Concentrations, doi:10.3334/CDIAC/atg.032, on CDIAC 2013
- Changes in stratospheric ozone have resulted in a decrease in radiative forcing of 0.05 W/m2: Forster, P.; et al., "Ch 2: Changes in Atmospheric Constituents and in Radiative Forcing", Table 2.12, in IPCC AR4 WG1 2007, p. 204. Referred to by: Blasing, T. J. (February 2013), Current Greenhouse Gas Concentrations, doi:10.3334/CDIAC/atg.032, on CDIAC 2013
- For SF
6 data from January 2004 onward see: . For data from 1995 through 2004, see the National Oceanic and Atmospheric Administration (NOAA), Halogenated and other Atmospheric Trace Species (HATS) site at: . Concentrations of SF
6 from 1970 through 1999, obtained from Antarctic firn (consolidated deep snow) air samples, can be found in W. T. Sturges et al.
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- The official greenhouse gas emissions data of developed countries from the UNFCCC
- Greenhouse gas at DMOZ
- Annual Greenhouse Gas Index (AGGI) from NOAA
- Atmospheric spectra of GHGs and other trace gases
- How Much Greenhouse Gas Does the United States Emit?
Carbon dioxide emissions
- International Energy Annual: Reserves
- Trends in Atmospheric Carbon Dioxide at NOAA
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