Pyrophosphoric acid
Chemical structure of pyrophosphoric acid | |
Names | |
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IUPAC names
Diphosphoric acid
μ-oxido-bis(dihydroxidooxidophosphorus) |
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Other names
Diphosphoric acid
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Identifiers | |
2466-09-3 | |
ChEBI | CHEBI:29888 |
ChEMBL | ChEMBL1160571 |
ChemSpider | 996 |
3151 | |
Jmol 3D model | Interactive image |
PubChem | 1023 |
UNII | 4E862E7GRQ |
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Properties | |
H4P2O7 | |
Molar mass | 177.98 g/mol |
Melting point | 71.5 °C (160.7 °F; 344.6 K) |
Extremely soluble | |
Solubility | Very soluble in alcohol, ether |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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verify (what is ?) | |
Infobox references | |
Pyrophosphoric acid, also known under the name diphosphoric acid, is colorless, odorless, hygroscopic and is soluble in water, diethyl ether, and ethyl alcohol. The anhydrous acid has two different forms, which melt at 54.3°C and 71.5°C. It is best prepared by ion exchange from sodium pyrophosphate or by reacting hydrogen sulfide with lead pyrophosphate. When phosphoric acid is dehydrated pyrophosphoric acid is produced as one of the products. When molten pyrophosphoric acid rapidly forms an equilibrium mixture of phosphoric acid, pyrophosphoric acid and polyphosphoric acids. The percentage by weight of pyrophosphoric acid is around 40% and it is difficult to recrystallise from the melt. In aqueous solution pyrophosphoric acid like all polyphosphoric acids hydrolyses and eventually an equilibrium is established between phosphoric acid pyrophosphoric acid and polyphosphoric acids. When highly diluted an aqueous solution of pyrophosphoric acid contains only phosphoric acid.[1]
- H4P2O7 + H2O ⇌ 2H3PO4
Pyrophosphoric acid is a medium strong inorganic acid. Anions, salts, and esters of pyrophosphoric acid are called pyrophosphates.
While pyrophosporic acid is corrosive, it is not known to be otherwise toxic.[2]
Contents
History
The name pyrophosphoric acid was given by a "Mr. Clarke of Glasgow" in 1827 who is credited with its discovery following the heating to red heat of a sodium phosphate salt. It was found that phosphoric acid when heated to red heat formed pyrophosphoric acid that was readily converted to phosphoric acid by hot water.[3]
See also
- Sodium pyrophosphate
- Calcium pyrophosphate dihydrate deposition disease
- Dimethylallyl pyrophosphate
- ADP
- ATP
- Ortho acids
- triphosphoric acid
References
- ↑ Lua error in package.lua at line 80: module 'strict' not found. – via ScienceDirect (Subscription may be required or content may be available in libraries.)
- ↑ Material Safety Data Sheet: Pyrophosphoric acid MSDS www,sciencelab.com
- ↑ Lua error in package.lua at line 80: module 'strict' not found.
External links
- Pages containing links to subscription-or-libraries content
- Pages with broken file links
- Articles without KEGG source
- Pages using collapsible list with both background and text-align in titlestyle
- Chemical articles using a fixed chemical formula
- Hydrogen compounds
- Phosphates
- Phosphorus oxoacids
- Acid anhydrides