Silver trifluoromethanesulfonate

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Silver trifluoromethanesulfonate
Silver triflate.png
Names
IUPAC name
silver trifluoromethanesulfonate
Other names
Silver triflate
Identifiers
2923-28-6changed
Jmol 3D model Interactive image
PubChem 76223
  • C(F)(F)(F)S(=O)(=O)[O-].[Ag+]
Properties
CF3SO3Ag
Molar mass 256.937 g/mol
Odor odorless
Melting point 286 °C (547 °F; 559 K)
soluble
Vapor pressure {{{value}}}
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references

Silver trifluoromethanesulfonate, or silver triflate is the triflate salt of silver. Since the triflate anion is weakly coordinating, it is useful as a halide abstraction reagent. This is similar to other silver salts, e.g. the tetrafluoroborate and the hexafluorophosphate. It is useful in activating sulfur protecting groups at the anomeric centres of carbohydrates, in presence of iodine/NIS.