Triisopropylphosphine

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Triisopropylphosphine
Names
Other names
Triisopropylphosphine
PiPr3
Pi-Pr3
Identifiers
6476-36-4 N
ChemSpider 73055 N
Jmol 3D model Interactive image
PubChem 24863218
  • InChI=1S/C9H21P/c1-7(2)10(8(3)4)9(5)6/h7-9H,1-6H3 N
    Key: IGNTWNVBGLNYDV-UHFFFAOYSA-N N
  • InChI=1/C9H21P/c1-7(2)10(8(3)4)9(5)6/h7-9H,1-6H3
    Key: IGNTWNVBGLNYDV-UHFFFAOYAM
  • CC(C)P(C(C)C)C(C)C
Properties
C9H21P
Molar mass 160.24 g mol−1
Appearance colourless liquid
Density 0.839 g/mL
Boiling point 81 °C (178 °F; 354 K) (22 mm Hg)
good in alkanes
Vapor pressure {{{value}}}
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
N verify (what is YesYN ?)
Infobox references

Triisopropylphosphine is the tertiary phosphine with the formula P(CH(CH3)2)3. Commonly used as a ligand in organometallic chemistry, it is often abbreviated to Pi-Pr3 or PiPr3. This ligand is one of the most basic alkyl phosphines with a large ligand cone angle of 160.[1]

Pi-Pr3 is similar to the more frequently used tricyclohexylphosphine. The triisopropyl derivative however, is a liquid at room temperature and more soluble in hydrocarbons.

References

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