Trost ligand
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Names | |
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IUPAC name
(1R,2R)-(+)-1,2-diaminocyclohexane-N,N'-bis(2-diphenylphosphinobenzoyl)
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Other names
Trost's ligand
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Identifiers | |
138517-61-0 | |
ChemSpider | 9138733 |
Jmol 3D model | Interactive image |
PubChem | 10963521 |
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Properties | |
C44H40N2O2P2 | |
Molar mass | 690.75 g/mol |
Appearance | white solid |
Melting point | 136 to 142 °C (277 to 288 °F; 409 to 415 K) |
insoluble; soluble in organic solvents, e.g. acetonitrile, dichloromethane, 1,4-dioxane, methanol, tetrahydrofuran, toluene | |
Vapor pressure | {{{value}}} |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references | |
The Trost ligand is a chiral ligand pioneered by Barry Trost for use in the palladium-catalyzed Trost asymmetric allylic alkylation. Other C2-symmetric ligands derived from trans-1,2-diaminocyclohexane (DACH) have also been developed by the Trost group, such as the (R,R)-DACH-naphthyl ligand derived from 2-diphenylphosphino-1-naphthalenecarboxylic acid. Related bidentate phosphine-containing ligands derived from other chiral diamines have also been developed for applications in asymmetric synthesis.
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