4,4'-Difluorobenzophenone

4,4'-Difluorobenzophenone

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Identifiers
CAS Number	345-92-6
ChemSpider	9206 Y
Jmol 3D model	Interactive image
InChI InChI=1S/C13H8F2O/c14-11-5-1-9(2-6-11)13(16)10-3-7-12(15)8-4-10/h1-8H Y Key: LSQARZALBDFYQZ-UHFFFAOYSA-N Y InChI=1/C13H8F2O/c14-11-5-1-9(2-6-11)13(16)10-3-7-12(15)8-4-10/h1-8H Key: LSQARZALBDFYQZ-UHFFFAOYAZ
SMILES O=C(c1ccc(F)cc1)c2ccc(F)cc2
Properties
Chemical formula	C13H8OF2
Molar mass	218.20 g/mol
Appearance	Colorless Solid
Melting point	107.5 to 108.5 °C (225.5 to 227.3 °F; 380.6 to 381.6 K)
Vapor pressure	{{{value}}}
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references

4,4’-Difluorobenzophenone is an organic compound with the formula of (FC₆H₄)₂CO. This a colorless solid is commonly used as a precursor to PEEK, or polyetherether ketone, a so-called high performance polymer. Because PEEK is resistant to attack, it is commonly used in carbon fiber coatings and cable insulation.

Synthesis

4,4’-Difluorobenzophenone is prepared by the acylation of fluorobenzene with p-fluorobenzoyl chloride. The conversion is typically conducted in the presence of an aluminium chloride catalyst in a petroleum ether solvent.

FC₆H₅C(O)Cl + C₆H₅F → (FC₆H₄)₂CO + HCl

Uses

The polymer PEEK is generated from the reaction of 4,4'-difluorobenzophenone with the salts of 1,4-benzenediol.

C₆H₄(ONa)₂ + (FC₆H₄)₂CO → 1/n[(C₆H₄O₂)(C₁₃H₈O)]_n + 2 NaF