Hexanitrodiphenylamine

Hexanitrodiphenylamine

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Names
IUPAC name 2,4,6-Trinitro-N-(2,4,6-trinitrophenyl)aniline
Other names HNDA; HNDPA; Dipicrylamine; Hexamine; hexil; hexyl; hexite; hexamin; GE - Hexa; IT - Esanitro difenilamina
Identifiers
CAS Number	131-73-7 Y
Jmol 3D model	Interactive image
PubChem	8576
SMILES C1=C(C=C(C(=C1[N+](=O)[O-])NC2=C(C=C(C=C2[N+](=O)[O-])[N+](=O)[O-])[N+](=O)[O-])[N+](=O)[O-])[N+](=O)[O-]
Properties
Chemical formula	C12H5N7O12
Molar mass	439.21 g·mol−1
Appearance	Crystalline solid. Yellow to orange. As ordinarily manufactured, it is yellow brown.
Density	1.64 g/cm3 (pressed)
Melting point	243 to 245 °C; 469 to 473 °F; 516 to 518 K with decomposition
Solubility in water	Soluble in acetone, warm glacial acetic acid, nitric acid, or aqueous alkalies except potassium hydroxide.
Vapor pressure	{{{value}}}
Explosive data
Detonation velocity	7100 m/s
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references

Hexanitrodiphenylamine (abbreviated HND), is an explosive chemical compound with the formula C₁₂H₅N₇O₁₂. HND was used extensively by the Japanese during World War II but was discontinued due to its toxicity.

Preparation

Dinitrodiphenylamine is treated with 98% nitric acid. The starting material, dinitrodiphenylamine, is obtained from the reaction of aniline, dinitrochlorobenzene, and soda ash.

Applications

HND is a booster-class explosive that was used in World War II by the Germans as a component of Hexanite (60% TNT - 40% HND) and by the Japanese as a component of Kongo (Type 98 H₂) (60% Trinitroanisol - 40% HND) for use in bombs, sea mines and depth charges; Seigate (Type 97 H) (60% TNT - 40% HND) for use in torpedo warheads and depth charges; and also in Otsu-B (60% TNT, 24% HND & 16% aluminium powder) for use in torpedo warheads.

Its ammonium salt, also known as Aurantia or Imperial Yellow, was discovered in 1873 by Emil Kopp and used as a yellow colorant for leather, wool and silk in the 19th and early 20th centuries.

Safety and toxicity

A most toxic and poisonous explosive, it attacks the skin, causing blisters which resemble burns. Dust from HND is injurious to the mucous membranes of the mouth, nose, and lungs.

See also

• Hexanite