Poly(methyl acrylate)

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Poly(methyl acrylate)
Poly(methyl acrylate)skeletaldiagramprimitive.png
Names
Other names
Polymethylacrylate
Polymethyl acrylate
Identifiers
9003-21-8
Abbreviations PMA
ChEBI CHEBI:60755
Properties
(C4H6O2)n
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

Poly(methyl acrylate) (PMA) is a hydrophobic synthetic acrylate polymer. PMA, though softer than polymethyl methacrylate (PMMA),[1] is tough, leathery, and flexible.[2]

It has a low glass-transition temperature about 10°C (12.5°C in case of PMA38).[3]

High-energy radiation leads to cross linking in PMA. However in polymethyl methacrylate (PMMA), a compound similar to PMA, degradation occurs instead.[1]

It is soluble in dimethyl sulfoxide (DMSO).[3] PMA is water-sensitive and unlike PMMA, is not stable against alkalies.[2]

It is used as macroinitiator to initiate the copolymerisation of HEMA and DMAEMA.[3] Also used in leather finishing and textiles.[2]

References

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