Cadmium acetate

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Cadmium acetate
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Names
IUPAC name
Cadmium acetate
Other names
Cadmium diacetate
Identifiers
543-90-8 YesY
5743-04-4 (dihydrate) N
ChemSpider 10521 YesY
EC Number 208-853-2
Jmol 3D model Interactive image
PubChem 10986
RTECS number AF7505000
  • InChI=1S/2C2H4O2.Cd/c2*1-2(3)4;/h2*1H3,(H,3,4);/q;;+2/p-2 YesY
    Key: LHQLJMJLROMYRN-UHFFFAOYSA-L YesY
  • InChI=1/2C2H4O2.Cd/c2*1-2(3)4;/h2*1H3,(H,3,4);/q;;+2/p-2
    Key: LHQLJMJLROMYRN-NUQVWONBAK
  • [Cd+2].[O-]C(=O)C.[O-]C(=O)C
Properties
Cd(CH3COO)2 (anhydrous)
Cd(CH3COO)2·2H2O (dihydrate)
Molar mass 230.500 g/mol (anhydrous)
266.529 g/mol (dihydrate)
Appearance colorless crystals (anhydrous)
white crystals (dihydrate)
Odor acetic acid
Density 2.341 g/cm3 (anhydrous)
2.01 g/cm3 (dihydrate)
Melting point 255 °C (491 °F; 528 K) (anhydrous) dihydrate decomposes at 130°C [1]
soluble (anhydrous), very soluble (dihydrate)
Solubility soluble in methanol, ethanol (anhydrous)
soluble in ethanol (dihydrate)
Structure
monoclinic
Vapor pressure {{{value}}}
Related compounds
Other anions
Cadmium fluoride
Cadmium chloride
Cadmium bromide
Cadmium iodide
Other cations
Zinc acetate
Mercury(II) acetate
Silver acetate
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
N verify (what is YesYN ?)
Infobox references

Cadmium acetate is the chemical compound with the formula Cd(CH3CO2)2. This colourless solid is classified coordination polymer, featuring acetate ligands interconnecting cadmium centers. The compound exists in anhydrous form and as a dihydrate. It forms by treating cadmium oxide with acetic acid:[2][3]

CdO + 2 CH3COOH → Cd(CH3COO)2 + H2O

Uses

Cadmium acetate is used for glazing ceramics and pottery; in electroplating baths, in dyeing and printing textiles; and as an analytic reagent for sulfur, selenium and tellurium.[3]

Preparation

Cadmium acetate is prepared by treating cadmium oxide with acetic acid. The compound may also be prepared by treating cadmium nitrate with acetic anhydride.

Safety

Cadmium compounds are considered Group 1 carcinogens by the IARC.

References

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