Clebsch–Gordan coefficients

In physics, the Clebsch–Gordan (CG) coefficients are numbers that arise in angular momentum coupling in quantum mechanics. They appear as the expansion coefficients of total angular momentum eigenstates in an uncoupled tensor product basis. In more mathematical terms, the CG coefficients are used in representation theory, particularly of compact Lie groups, to perform the explicit direct sum decomposition of the tensor product of two irreducible representations into irreducible representations, in cases where the numbers and types of irreducible components are already known abstractly. The name derives from the German mathematicians Alfred Clebsch and Paul Gordan, who encountered an equivalent problem in invariant theory.

From a vector calculus perspective, the CG coefficients associated with the SO(3) group can be defined simply in terms of integrals of products of spherical harmonics and their complex conjugates. The addition of spins in quantum-mechanical terms can be read directly from this approach as spherical harmonics are eigenfunctions of total angular momentum and projection thereof onto an axis, and the integrals correspond to the Hilbert space inner product. From the formal definition of angular momentum, recursion relations for the Clebsch–Gordan coefficients can be found. There also exist complicated explicit formulas for their direct calculation.

The formulas below use Dirac's bra–ket notation and the Condon–Shortley phase convention is adopted.

Angular momentum operators

Angular momentum operators are self-adjoint operators j_x, j_y, and j_z that satisfy the commutation relations

$\begin{align} &[j_k, j_l] \equiv j_k j_l - j_l j_k = i \hbar \varepsilon_{klm} j_m & k, l, m &\in \{ x, y, z\} \end{align}$

where ε_klm is the Levi-Civita symbol. Together the three operators define a vector operator, a rank one Cartesian tensor operator,

$\mathbf j = (j_{x}, j_{y}, j_{z})$

It also known as a spherical vector, since it is also a spherical tensor operator. It is only for rank one that spherical tensor operators coincide with the Cartesian tensor operators.

By developing this concept further, one can define another operator j² as the inner product of j with itself:

$\mathbf j^2 = j_{x}^2 + j_{y}^2 + j_{\mathrm z}^2.$

This is an example of a Casimir operator. It is diagonal and its eigenvalue characterizes the particular irreducible representation of the angular momentum algebra so(3) ≅ su(2). This is physically interpreted as the square of the total angular momentum of the states on which the representation acts.

One can also define raising (j₊) and lowering (j₋) operators, the so-called ladder operators,

$j_\pm = j_{x} \pm ij_{y}.$

Angular momentum states

It can be shown from the above definitions that j² commutes with j_x, j_y, and j_z:

$\begin{align} &[\mathbf j^2, \mathrm j_k] = 0 & k &\in \{\mathrm x, \mathrm y, \mathrm z\} \end{align}$

When two Hermitian operators commute, a common set of eigenfunctions exists. Conventionally j² and j_z are chosen. From the commutation relations the possible eigenvalues can be found. These states are denoted |j m⟩ where j is the angular momentum quantum number and m is the angular momentum projection onto the z-axis. They satisfy the following eigenvalue equations:

$\begin{align} \mathbf j^2 |j \, m\rangle &= \hbar^2 j (j + 1) |j \, m\rangle & j &\in \{0, \tfrac{1}{2}, 1, \tfrac{3}{2}, \ldots\} \\ \mathrm j_{\mathrm z} |j \, m\rangle &= \hbar m |j \, m\rangle & m &\in \{-j, -j + 1, \ldots, j\}. \end{align}$

The raising and lowering operators can be used to alter the value of m:

$\mathrm j_\pm |j \, m\rangle = \hbar C_\pm(j, m) |j \, (m \pm 1)\rangle$

where the ladder coefficient is given by:

$C_\pm(j, m) = \sqrt{j (j + 1) - m (m \pm 1)} = \sqrt{(j \mp m)(j \pm m + 1)}.$

(1)

In principle, one may also introduce a (possibly complex) phase factor in the definition of $C_\pm(j, m)$. The choice made in this article is in agreement with the Condon–Shortley phase convention. The angular momentum states are orthogonal (because their eigenvalues with respect to a Hermitian operator are distinct) and are assumed to be normalized:

$\langle j \, m | j' \, m' \rangle = \delta_{j, j'} \delta_{m, m'}.$

Here the italicized j and m denote integer or half-integer eigenvalues of some angular momentum (orbital, spin or total) of a particle or of the system. On the other hand, the roman j_x, j_y, j_z, j₊, j₋, and j² denote operators.

Tensor product space

We now consider systems with two physically different angular momenta j₁ and j₂. Examples include the spin and the orbital angular momentum of a single electron, or the spins of two electrons, or the orbital angular momenta of two electrons.

Let V₁ be the (2 j₁ + 1)-dimensional vector space spanned by the states

$\begin{align} &|j_1 \, m_1\rangle & m_1 &\in \{-j_1, -j_1 + 1, \ldots, j_1\} \end{align}$,

and V₂ the (2 j₂ + 1)-dimensional vector space spanned by the states

$\begin{align} &|j_2 \, m_2\rangle & m_2 &\in \{-j_2, -j_2 + 1, \ldots, j_2\} \end{align}$.

The tensor product of these spaces, V₃ ≡ V₁ ⊗ V₂, has a (2 j₁ + 1) (2 j₂ + 1)-dimensional uncoupled basis

$|j_1 \, m_1 \, j_2 \, m_2\rangle \equiv |j_1 \, m_1\rangle \otimes |j_2 \, m_2\rangle \quad (m_1 \in \{-j_1, -j_1 + 1, \ldots, j_1\}) \quad (m_2 \in \{-j_2, -j_2 + 1, \ldots, j_2\}$.

Angular momentum operators are defined to act on states in V₃ in the following manner:

$(\mathbf j \otimes 1) |j_1 \, m_1 \, j_2 \, m_2\rangle \equiv \mathbf j |j_1 \, m_1\rangle \otimes |j_2 \, m_2\rangle$

and

$(1 \otimes \mathrm \mathbf j) |j_1 \, m_1 \, j_2 \, m_2\rangle \equiv |j_1 \, m_1\rangle \otimes \mathbf j |j_2 \, m_2\rangle$

where 1 denotes the identity operator.

The total angular momentum operators are defined by

$\mathbf J \equiv \mathbf j \otimes 1 + 1 \otimes \mathbf j$

The total angular momentum operators can be shown to satisfy the same kind of commutation relations:

$[\mathrm J_k, \mathrm J_l] = i \hbar \varepsilon_{k, l, m} \mathrm J_m$,

where k, l, m ∈ {x, y, z}. Hence, a set of coupled eigenstates exist for the total angular momentum operator as well:

$\begin{align} \mathbf{J}^2 |[j_1 \, j_2] \, J \, M\rangle &= \hbar^2 J (J + 1) |[j_1 \, j_2] \, J \, M\rangle \\ \mathrm{J}_z |[j_1 \, j_2] \, J \, M\rangle &= \hbar M |[j_1 \, j_2] \, J \, M\rangle \end{align}$

for M ∈ {−J, −J + 1, …, J}. Note that it is common to omit the [j₁ j₂] part.

The total angular momentum quantum number J must satisfy the triangular condition that:

$|j_1 - j_2| \leq J \leq j_1 + j_2$,

such that the three nonnegative integer or half-integer values could correspond to the three sides of a triangle.

The total number of total angular momentum eigenstates is necessarily equal to the dimension of V₃:

$\sum_{J = |j_1 - j_2|}^{j_1 + j_2} (2 J + 1) = (2 j_1 + 1) (2 j_2 + 1)$.

The total angular momentum states form an orthonormal basis of V₃:

$\langle J_1 \, M_1 | J_2 \, M_2 \rangle = \delta_{J_1, J_2} \delta_{M_1, M_2}$.

Formal definition of Clebsch–Gordan coefficients

The coupled states can be expanded via the completeness relation (resolution of identity) in the uncoupled basis

$|[j_1 \, j_2] \, J \, M\rangle = \sum_{m_1 = -j_1}^{j_1} \sum_{m_2 = -j_2}^{j_2} |j_1 \, m_1 \, j_2 \, m_2\rangle \langle j_1 \, m_1 \, j_2 \, m_2 | J \, M\rangle$

(2)

The expansion coefficients

$\langle j_1 \, m_1 \, j_2 \, m_2 | J \, M \rangle$

are the Clebsch–Gordan coefficients. Note that some authors write them in a different order such as ⟨j₁ j₂; m₁ m₂|J M⟩.

Applying the operator

$\mathrm J_{\mathrm z} = \mathrm j_{\mathrm z} \otimes 1 + 1 \otimes \mathrm j_{\mathrm z}$

to both sides of the defining equation shows that the Clebsch–Gordan coefficients can only be nonzero when

$M = m_1 + m_2$.

Recursion relations

The recursion relations were discovered by physicist Giulio Racah from the Hebrew University of Jerusalem in 1941.

Applying the total angular momentum raising and lowering operators

$\mathrm J_\pm = \mathrm j_\pm \otimes 1 + 1 \otimes \mathrm j_\pm$

to the left hand side of the defining equation gives

$\begin{align} \mathrm J_\pm |[j_1 \, j_2] \, J \, M\rangle &= \hbar C_\pm(J, M) |[j_1 \, j_2] \, J \, (M \pm 1)\rangle \\ &= \hbar C_\pm(J, M) \sum_{m_1, m_2} |j_1 \, m_1 \, j_2 \, m_2\rangle \langle j_1 \, m_1 \, j_2 \, m_2 | J \, (M \pm 1)\rangle \end{align}$

Applying the same operators to the right hand side gives

$\begin{align} & \mathrm J_\pm \sum_{m_1, m_2} |j_1 \, m_1 \, j_2 \, m_2\rangle \langle j_1 \, m_1 \, j_2 \, m_2 | J \, M\rangle \\ &= \hbar \sum_{m_1, m_2} \Bigl( C_\pm(j_1, m_1) |j_1 \, (m_1 \pm 1) \, j_2 \, m_2\rangle + C_\pm(j_2, m_2) |j_1 \, m_1 \, j_2 \, (m_2 \pm 1)\rangle \Bigr) \langle j_1 \, m_1 \, j_2 \, m_2 | J \, M\rangle \\ &= \hbar \sum_{m_1, m_2} |j_1 \, m_1 \, j_2 \, m_2\rangle \Bigl( C_\pm(j_1, m_1 \mp 1) \langle j_1 \, (m_1 \mp 1) \, j_2 \, m_2 | J \, M\rangle + C_\pm(j_2, m_2 \mp 1) \langle j_1 \, m_1 \, j_2 \, (m_2 \mp 1) | J \, M\rangle \Bigr) \text{.} \end{align}$

where C_± was defined in 1. Combining these results gives recursion relations for the Clebsch–Gordan coefficients:

$C_\pm(J, M) \langle j_1 \, m_1 \, j_2 \, m_2 | J \, (M \pm 1)\rangle = C_\pm(j_1, m_1 \mp 1) \langle j_1 \, (m_1 \mp 1) \, j_2 \, m_2 | J \, M\rangle + C_\pm(j_2, m_2 \mp 1) \langle j_1 \, m_1 \, j_2 \, (m_2 \mp 1) | J \, M\rangle$.

Taking the upper sign with the condition that M = J gives initial recursion relation:

$0 = C_+(j_1, m_1 - 1) \langle j_1 \, (m_1 - 1) \, j_2 \, m_2 | J \, J\rangle + C_+(j_2, m_2 - 1) \langle j_1 \, m_1 \, j_2 \, (m_2 - 1) | J \, J\rangle$.

In the Condon–Shortley phase convention, one adds the constraint that

$\langle j_1 \, j_1 \, j_2 \, (J - j_1) | J \, J\rangle > 0$

(and is therefore also real).

The Clebsch–Gordan coefficients ⟨j₁ m₁ j₂ m₂ | J J⟩ can then be found from these recursion relations. The normalization is fixed by the requirement that the sum of the squares, which equivalent to the requirement that the norm of the state |[j₁ j₂] J J⟩ must be one.

The lower sign in the recursion relation can be used to find all the Clebsch–Gordan coefficients with M = J − 1. Repeated use of that equation gives all coefficients.

This procedure to find the Clebsch–Gordan coefficients shows that they are all real in the Condon–Shortley phase convention.

Explicit expression

For an explicit expression of the Clebsch–Gordan coefficients and tables with numerical values, see table of Clebsch–Gordan coefficients.

Orthogonality relations

These are most clearly written down by introducing the alternative notation

$\langle J \, M | j_1 \, m_1 \, j_2 \, m_2 \rangle \equiv \langle j_1 \, m_1 \, j_2 \, m_2 | J \, M \rangle$

The first orthogonality relation is

$\sum_{J = |j_1 - j_2|}^{j_1 + j_2} \sum_{M = -J}^J \langle j_1 \, m_1 \, j_2 \, m_2 | J \, M \rangle \langle J \, M | j_1 \, m_1' \, j_2 \, m_2' \rangle = \langle j_1 \, m_1 \, j_2 \, m_2 | j_1 \, m_1' \, j_2 \, m_2' \rangle = \delta_{m_1, m_1'} \delta_{m_2, m_2'}$

(derived from the fact that 1 ≡ ∑_x |x⟩ ⟨x|) and the second one is

$\sum_{m_1, m_2} \langle J \, M | j_1 \, m_1 \, j_2 \, m_2 \rangle \langle j_1 \, m_1 \, j_2 \, m_2 | J' \, M' \rangle = \langle J \, M | J' \, M' \rangle = \delta_{J, J'} \delta_{M, M'}$.

Special cases

For J = 0 the Clebsch–Gordan coefficients are given by

$\langle j_1 \, m_1 \, j_2 \, m_2 | 0 \, 0 \rangle = \delta_{j_1, j_2} \delta_{m_1, -m_2} \frac{(-1)^{j_1 - m_1}}{\sqrt{2 j_2 + 1}}$.

For J = j₁ + j₂ and M = J we have

$\langle j_1 \, j_1 \, j_2 \, j_2 | (j_1 + j_2) \, (j_1 + j_2) \rangle = 1$.

For j₁ = j₂ = J / 2 and m₁ = −m₂ we have

$\langle j_1 \, m_1 \, j_1 \, (-m_1) | (2 j_1) \, 0 \rangle = \frac{(2 j_1)!^2}{(j_1 - m_1)! (j_1 + m_1)! \sqrt{(4 j_1)!}}$.

For j₁ = j₂ = m₁ = −m₂ we have

$\langle j_1 \, j_1 \, j_1 \, (-j_1) | J \, 0 \rangle = (2 j_1)! \sqrt{\frac{2 J + 1}{(J + 2 j_1 + 1)! (2 j_1 - J)!}}.$

For j₂ = 1, m₂ = 0 we have

$\begin{align} \langle j_1 \, m \, 1 \, 0 | (j_1 + 1) \, m \rangle &= \sqrt{\frac{(j_1 - m + 1) (j_1 + m + 1)}{(2 j_1 + 1) (j_1 + 1)}} \\ \langle j_1 \, m \, 1 \, 0 | j_1 \, m \rangle &= \frac{m}{\sqrt{j_1 (j_1 + 1)}} \\ \langle j_1 \, m \, 1 \, 0 | (j_1 - 1) \, m \rangle &= -\sqrt{\frac{(j_1 - m) (j_1 + m)}{j_1 (2 j_1 + 1)}} \end{align}$

Symmetry properties

$\begin{align} \langle j_1 \, m_1 \, j_2 \, m_2 | J \, M \rangle &= (-1)^{j_1 + j_2 - J} \langle j_1 \, (-m_1) \, j_2 \, (-m_2) | J \, (-M)\rangle \\ &= (-1)^{j_1 + j_2 - J} \langle j_2 \, m_2 \, j_1 \, m_1 | J \, M \rangle \\ &= (-1)^{j_1 - m_1} \sqrt{\frac{2 J + 1}{2 j_2 + 1}} \langle j_1 \, m_1 \, J \, (-M)| j_2 \, (-m_2) \rangle \\ &= (-1)^{j_2 + m_2} \sqrt{\frac{2 J + 1}{2 j_1 + 1}} \langle J \, (-M) \, j_2 \, m_2| j_1 \, (-m_1) \rangle \\ &= (-1)^{j_1 - m_1} \sqrt{\frac{2 J + 1}{2 j_2 + 1}} \langle J \, M \, j_1 \, (-m_1) | j_2 \, m_2 \rangle \\ &= (-1)^{j_2 + m_2} \sqrt{\frac{2 J + 1}{2 j_1 + 1}} \langle j_2 \, (-m_2) \, J \, M | j_1 \, m_1 \rangle \end{align}$

A convenient way to derive these relations is by converting the Clebsch–Gordan coefficients to Wigner 3-j symbols using 3. The symmetry properties of Wigner 3-j symbols are much simpler.

Rules for phase factors

Care is needed when simplifying phase factors: a quantum number may be a half-integer rather than an integer, therefore (−1)^2k is not necessarily 1 for a given quantum number k unless it can be proven to be an integer. Instead, it is replaced by the following weaker rule:

$(-1)^{4 k} = 1$

for any angular-momentum-like quantum number k.

Nonetheless, a combination of j_i and m_i is always an integer, so the stronger rule applies for these combinations:

$(-1)^{2 (j_i - m_i)} = 1$

This identity also holds if the sign of either j_i or m_i or both is reversed.

It is useful to observe that any phase factor for a given (j_i, m_i) pair can be reduced to the canonical form:

$(-1)^{a j_i + b (j_i - m_i)}$

where a ∈ {0, 1, 2, 3} and b ∈ {0, 1} (other conventions are possible too). Converting phase factors into this form makes it easy to tell whether two phase factors are equivalent. (Note that this form is only locally canonical: it fails to take into account the rules that govern combinations of (j_i, m_i) pairs such as the one described in the next paragraph.)

An additional rule holds for combinations of j₁, j₂, and j₃ that are related by a Clebsch-Gordan coefficient or Wigner 3-j symbol:

$(-1)^{2 (j_1 + j_2 + j_3)} = 1$

This identity also holds if the sign of any j_i is reversed, or if any of them are substituted with an m_i instead.

Relation to Wigner 3-j symbols

Clebsch–Gordan coefficients are related to Wigner 3-j symbols which have more convenient symmetry relations.

$\langle j_1 \, m_1 \, j_2 \, m_2 | J \, M \rangle = (-1)^{j_1 - j_2 + M} \sqrt{2 J + 1} \begin{pmatrix} j_1 & j_2 & J \\ m_1 & m_2 & -M \end{pmatrix}$

(3)

Relation to Wigner D-matrices

$\begin{align} &\int_0^{2 \pi} d \alpha \int_0^\pi \sin \beta \, d\beta \int_0^{2 \pi} d \gamma \, D^J_{M, K}(\alpha, \beta, \gamma)^* D^{j_1}_{m_1, k_1}(\alpha, \beta, \gamma) D^{j_2}_{m_2, k_2}(\alpha, \beta, \gamma) \\ &= \frac{8 \pi^2}{2 J + 1} \langle j_1 \, m_1 \, j_2 \, m_2 | J \, M \rangle \langle j_1 \, k_1 \, j_2 \, k_2 | J \, K \rangle \end{align}$

Relation to spherical harmonics

In the case where integers are involved, the coefficients can be related to integrals of spherical harmonics:

$\int_{4 \pi} Y_{\ell_1}^{m_1}{}^*(\Omega) Y_{\ell_2}^{m_2}{}^*(\Omega) Y_L^M (\Omega) \, d \Omega = \sqrt{\frac{(2 \ell_1 + 1) (2 \ell_2 + 1)}{4 \pi (2 L + 1)}} \langle \ell_1 \, 0 \, \ell_2 \, 0 | L \, 0 \rangle \langle \ell_1 \, m_1 \, \ell_2 \, m_2 | L \, M \rangle$

It follows from this and orthonormality of the spherical harmonics that CG coefficients are in fact the expansion coefficients of a product of two spherical harmonics in terms a single spherical harmonic:

$Y_{\ell_1}^{m_1}(\Omega) Y_{\ell_2}^{m_2}(\Omega) = \sum_{L, M} \sqrt{\frac{(2 \ell_1 + 1) (2 \ell_2 + 1)}{4 \pi (2 L + 1)}} \langle \ell_1 \, 0 \, \ell_2 \, 0 | L \, 0 \rangle \langle \ell_1 \, m_1 \, \ell_2 \, m_2 | L \, M \rangle Y_L^M (\Omega)$

Other Properties

$\sum_m (-1)^{j - m} \langle j \, m \, j \, (-m) | J \, 0 \rangle = \delta_{J, 0} \sqrt{2 j + 1}$

SU(N) Clebsch–Gordan coefficients

For arbitrary groups and their representations, Clebsch–Gordan coefficients are not known in general. However, algorithms to produce Clebsch–Gordan coefficients for the special unitary group are known. In particular, SU(3) Clebsch-Gordan coefficients have been computed and tabulated because of their utility in characterizing hadronic decays, where a flavor-SU(3) symmetry exists that relates the up, down, and strange quarks. A web interface for tabulating SU(N) Clebsch–Gordan coefficients is readily available.

See also

• 3-jm symbol
• Racah W-coefficient
• 6-j symbol
• 9-j symbol
• Spherical harmonics
• Spherical basis
• Associated Legendre polynomials
• Angular momentum
• Angular momentum coupling
• Total angular momentum quantum number
• Azimuthal quantum number
• Table of Clebsch–Gordan coefficients
• Wigner D-matrix
• Angular momentum diagrams (quantum mechanics)
• Clebsch–Gordan coefficient for SU(3)

External links

• PDF Table of Clebsch–Gordan Coefficients, Spherical Harmonics, and d-Functions
• Clebsch–Gordan, 3-j and 6-j Coefficient Web Calculator
• Downloadable Clebsch–Gordan Coefficient Calculator for Mac and Windows
• Web interface for tabulating SU(N) Clebsch–Gordan coefficients

Further reading

• Quantum mechanics, E. Zaarur, Y. Peleg, R. Pnini, Schaum's Easy Oulines Crash Course, McGraw Hill (USA), 2006, ISBN (10-)007-145533-7 ISBN (13-)978-007-145533-6
• Quantum Physics of Atoms, Molecules, Solids, Nuclei, and Particles (2nd Edition), R. Eisberg, R. Resnick, John Wiley & Sons, 1985, ISBN 978-0-471-87373-0
• Quantum Mechanics, E. Abers, Pearson Ed., Addison Wesley, Prentice Hall Inc, 2004, ISBN 978-0-13-146100-0
• Physics of Atoms and Molecules, B. H. Bransden, C. J. Joachain, Longman, 1983, ISBN 0-582-44401-2
• The Cambridge Handbook of Physics Formulas, G. Woan, Cambridge University Press, 2010, ISBN 978-0-521-57507-2.
• Encyclopaedia of Physics (2nd Edition), R. G. Lerner, G. L. Trigg, VHC publishers, 1991, ISBN (Verlagsgesellschaft) 3-527-26954-1, ISBN (VHC Inc.) 0-89573-752-3
• McGraw Hill Encyclopaedia of Physics (2nd Edition), C. B. Parker, 1994, ISBN 0-07-051400-3