Diisopropyl tartrate

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Diisopropyl tartrate
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Names
IUPAC name
Diisopropyl tartrate
Other names
Bis(1-methylethyl) ester of 2,3-dihydroxybutanedioic acid, Dipropan-2-yl 2,3-dihydroxybutanedioate, DIPT
Identifiers
2217-15-4 YesY
ChemSpider 101254 (−)-isomer N
EC Number 218-709-0
Jmol 3D model (−)-isomer: Interactive image
Interactive image
PubChem 102768 (−)-isomer
112972
  • (−)-isomer: InChI=1S/C10H18O6/c1-5(2)15-9(13)7(11)8(12)10(14)16-6(3)4/h5-8,11-12H,1-4H3/t7-,8-/m0/s1 N
    Key: XEBCWEDRGPSHQH-YUMQZZPRSA-N N
  • (−)-isomer: CC(C)OC(=O)C(C(C(=O)OC(C)C)O)O
  • O=C(OC(C)C)[C@@H](O)[C@H](O)C(=O)OC(C)C
Properties
C10H18O6
Molar mass 234.25 g/mol
Boiling point 152 °C (306 °F; 425 K) at 16 kPa
Vapor pressure {{{value}}}
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
N verify (what is YesYN ?)
Infobox references

Diisopropyl tartrate (DIPT) is a diester of tartaric acid. It has a two chiral carbon atoms giving rise to three stereoisomeric variants. It is commonly used in asymmetric synthesis as a catalyst and as chiral building block for pharmaceuticals and agrochemicals. Its main application is in Sharpless epoxidation, where it serves as a chiral ligand to titanium after reaction with titanium isopropoxide.[1]

References

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