Isotopes of californium
Actinides and fission products by half-life
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---|---|---|---|---|---|---|---|---|
Actinides[1] by decay chain | Half-life range (y) |
Fission products of 235U by yield[2] | ||||||
4n | 4n+1 | 4n+2 | 4n+3 | |||||
4.5–7% | 0.04–1.25% | <0.001% | ||||||
228Ra№ | 4–6 | † | 155Euþ | |||||
244Cm | 241Puƒ | 250Cf | 227Ac№ | 10–29 | 90Sr | 85Kr | 113mCdþ | |
232Uƒ | 238Pu№ | 243Cmƒ | 29–97 | 137Cs | 151Smþ | 121mSn | ||
248Bk[3] | 249Cfƒ | 242mAmƒ | 141–351 |
No fission products |
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241Amƒ | 251Cfƒ[4] | 430–900 | ||||||
226Ra№ | 247Bk | 1.3 k – 1.6 k | ||||||
240Pu | 229Th№ | 246Cm | 243Amƒ | 4.7 k – 7.4 k | ||||
245Cmƒ | 250Cm | 8.3 k – 8.5 k | ||||||
239Puƒ№ | 24.1 k | |||||||
230Th№ | 231Pa№ | 32 k – 76 k | ||||||
236Npƒ | 233Uƒ№ | 234U№ | 150 k – 250 k | ‡ | 99Tc₡ | 126Sn | ||
248Cm | 242Pu | 327 k – 375 k | 79Se₡ | |||||
1.53 M | 93Zr | |||||||
237Np№ | 2.1 M – 6.5 M | 135Cs₡ | 107Pd | |||||
236U№ | 247Cmƒ | 15 M – 24 M | 129I₡ | |||||
244Pu№ | 80 M |
... nor beyond 15.7 M years[5] |
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232Th№ | 238U№ | 235Uƒ№ | 0.7 G – 14.1 G | |||||
Legend for superscript symbols |
Californium (Cf) is an artificial element, and thus a standard atomic mass cannot be given. Like all artificial elements, it has no stable isotopes. The first isotope to be synthesized was 245Cf in 1950. There are 20 known radioisotopes ranging from 237Cf to 256Cf and one nuclear isomer, 249mCf. The longest-lived isotope is 251Cf with a half-life of 900 years.
Contents
Californium-252
Californium-252 (Cf-252) undergoes spontaneous fission and is used in small sized neutron sources. Fission neutrons have an energy range of 0 to 13 MeV with a mean value of 2.3 MeV and a most probable value of 1 MeV.[6]
This isotope produces high neutron emissions and can be used for a number of applications in industries such as nuclear energy, medicine, and petrochemical exploration. The neutron sources produced from Cf-252 are most notably used in the start-up of nuclear reactors.
Once a reactor is filled with nuclear fuel, the stable neutron emissions from the source material initiates the chain reaction known as fission.
Californium 252 has also been used in the treatment of serious forms of cancer. In patients suffering from certain types of brain and cervical cancer, Cf-252 can be used as a more cost-effective substitute for radium.[7]
Table
nuclide symbol |
Z(p) | N(n) | isotopic mass (u) |
half-life | decay mode(s)[8][n 1] |
daughter isotope(s) |
nuclear spin |
---|---|---|---|---|---|---|---|
excitation energy | |||||||
237Cf | 98 | 139 | 237.06207(54)# | 2.1(3) s | SF | (various) | 5/2+# |
β+ | 237Bk | ||||||
α | 233Cm | ||||||
238Cf | 98 | 140 | 238.06141(43)# | 21.1(13) ms | SF | (various) | 0+ |
β+ (rare) | 238Bk | ||||||
α (rare) | 234Cm | ||||||
239Cf | 98 | 141 | 239.06242(23)# | 60(30) s [39(+37−12) s] |
α | 235Cm | 5/2+# |
β+ (rare) | 239Bk | ||||||
240Cf | 98 | 142 | 240.06230(22)# | 1.06(15) min | α (98%) | 236Cm | 0+ |
SF (2%) | (various) | ||||||
β+ (rare) | 240Bk | ||||||
241Cf | 98 | 143 | 241.06373(27)# | 3.78(70) min | β+ (75%) | 241Bk | 7/2−# |
α (25%) | 237Cm | ||||||
242Cf | 98 | 144 | 242.06370(4) | 3.49(15) min | α (80%) | 238Cm | 0+ |
β+ (20%) | 242Bk | ||||||
SF (.014%) | (various) | ||||||
243Cf | 98 | 145 | 243.06543(15)# | 10.7(5) min | β+ (86%) | 243Bk | (1/2+) |
α (14%) | 239Cm | ||||||
244Cf | 98 | 146 | 244.066001(3) | 19.4(6) min | α (99%) | 240Cm | 0+ |
EC (1%) | 244Bk | ||||||
245Cf | 98 | 147 | 245.068049(3) | 45.0(15) min | β+ (64%) | 245Bk | (5/2+) |
α (36%) | 241Cm | ||||||
246Cf | 98 | 148 | 246.0688053(22) | 35.7(5) h | α | 242Cm | 0+ |
EC (5×10−4%) | 246Bk | ||||||
SF (2×10−4%) | (various) | ||||||
247Cf | 98 | 149 | 247.071001(9) | 3.11(3) h | EC (99.96%) | 247Bk | (7/2+)# |
α (.04%) | 243Cm | ||||||
248Cf | 98 | 150 | 248.072185(6) | 333.5(28) d | α (99.99%) | 244Cm | 0+ |
SF (.0029%) | (various) | ||||||
249Cf | 98 | 151 | 249.0748535(24) | 351(2) y | α | 245Cm | 9/2− |
SF (5×10−7%) | (various) | ||||||
249mCf | 144.98(5) keV | 45(5) µs | 5/2+ | ||||
250Cf | 98 | 152 | 250.0764061(22) | 13.08(9) y | α (99.92%) | 246Cm | 0+ |
SF (.077%) | (various) | ||||||
251Cf[n 2] | 98 | 153 | 251.079587(5) | 900(40) y | α | 247Cm | 1/2+ |
252Cf[n 3] | 98 | 154 | 252.081626(5) | 2.645(8) y | α (96.9%) | 248Cm | 0+ |
SF (3.09%)[n 4] | (various) | ||||||
253Cf | 98 | 155 | 253.085133(7) | 17.81(8) d | β− (99.69%) | 253Es | (7/2+) |
α (.31%) | 249Cm | ||||||
254Cf | 98 | 156 | 254.087323(13) | 60.5(2) d | SF (99.69%) | (various) | 0+ |
α (.31%) | 250Cm | ||||||
β−β− (rare) | 254Fm | ||||||
255Cf | 98 | 157 | 255.09105(22)# | 85(18) min | β− (99.99%) | 255Es | (7/2+) |
SF (.001%) | (various) | ||||||
α (10−5%) | 251Cm | ||||||
256Cf | 98 | 158 | 256.09344(32)# | 12.3(12) min | SF (99%) | (various) | 0+ |
β− (1%) | 256Es | ||||||
α (10−6%) | 252Cm | ||||||
β−β− (rare) | 256Fm |
- ↑ Abbreviations:
EC: Electron capture
SF: Spontaneous fission - ↑ High neutron cross-section, tends to absorb neutrons
- ↑ Most common isotope
- ↑ High neutron emitter, average 3.7 neutrons per fission
Notes
- Values marked # are not purely derived from experimental data, but at least partly from systematic trends. Spins with weak assignment arguments are enclosed in parentheses.
- Uncertainties are given in concise form in parentheses after the corresponding last digits. Uncertainty values denote one standard deviation, except isotopic composition and standard atomic mass from IUPAC, which use expanded uncertainties.
References
- ↑ Plus radium (element 88). While actually a sub-actinide, it immediately precedes actinium (89) and follows a three-element gap of instability after polonium (84) where no isotopes have half-lives of at least four years (the longest-lived isotope in the gap is radon-222 with a half life of less than four days). Radium's longest lived isotope, at 1,600 years, thus merits the element's inclusion here.
- ↑ Specifically from thermal neutron fission of U-235, e.g. in a typical nuclear reactor.
- ↑ Lua error in package.lua at line 80: module 'strict' not found.
"The isotopic analyses disclosed a species of mass 248 in constant abundance in three samples analysed over a period of about 10 months. This was ascribed to an isomer of Bk248 with a half-life greater than 9 y. No growth of Cf248 was detected, and a lower limit for the β− half-life can be set at about 104 y. No alpha activity attributable to the new isomer has been detected; the alpha half-life is probably greater than 300 y." - ↑ This is the heaviest isotope with a half-life of at least four years before the "Sea of Instability".
- ↑ Excluding those "classically stable" isotopes with half-lives significantly in excess of 232Th; e.g., while 113mCd has a half-life of only fourteen years, that of 113Cd is nearly eight quadrillion years.
- ↑ Lua error in package.lua at line 80: module 'strict' not found.
- ↑ Lua error in package.lua at line 80: module 'strict' not found.
- ↑ Lua error in package.lua at line 80: module 'strict' not found.
- Isotope masses from:
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- Isotopic compositions and standard atomic masses from:
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- Half-life, spin, and isomer data selected from the following sources. See editing notes on this article's talk page.
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- Lua error in package.lua at line 80: module 'strict' not found.
- Lua error in package.lua at line 80: module 'strict' not found.
- Other
Isotopes of berkelium | Isotopes of californium | Isotopes of einsteinium |
Table of nuclides |
Isotopes of the chemical elements | |||||||||||||||||
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1 H |
2 He |
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3 Li |
4 Be |
5 B |
6 C |
7 N |
8 O |
9 F |
10 Ne |
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11 Na |
12 Mg |
13 Al |
14 Si |
15 P |
16 S |
17 Cl |
18 Ar |
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19 K |
20 Ca |
21 Sc |
22 Ti |
23 V |
24 Cr |
25 Mn |
26 Fe |
27 Co |
28 Ni |
29 Cu |
30 Zn |
31 Ga |
32 Ge |
33 As |
34 Se |
35 Br |
36 Kr |
37 Rb |
38 Sr |
39 Y |
40 Zr |
41 Nb |
42 Mo |
43 Tc |
44 Ru |
45 Rh |
46 Pd |
47 Ag |
48 Cd |
49 In |
50 Sn |
51 Sb |
52 Te |
53 I |
54 Xe |
55 Cs |
56 Ba |
72 Hf |
73 Ta |
74 W |
75 Re |
76 Os |
77 Ir |
78 Pt |
79 Au |
80 Hg |
81 Tl |
82 Pb |
83 Bi |
84 Po |
85 At |
86 Rn |
|
87 Fr |
88 Ra |
104 Rf |
105 Db |
106 Sg |
107 Bh |
108 Hs |
109 Mt |
110 Ds |
111 Rg |
112 Cn |
113 Uut |
114 Fl |
115 Uup |
116 Lv |
117 Uus |
118 Uuo |
|
57 La |
58 Ce |
59 Pr |
60 Nd |
61 Pm |
62 Sm |
63 Eu |
64 Gd |
65 Tb |
66 Dy |
67 Ho |
68 Er |
69 Tm |
70 Yb |
71 Lu |
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89 Ac |
90 Th |
91 Pa |
92 U |
93 Np |
94 Pu |
95 Am |
96 Cm |
97 Bk |
98 Cf |
99 Es |
100 Fm |
101 Md |
102 No |
103 Lr |
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